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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Polypyrrole modified Fe0-loaded graphene oxide for the enrichment of uranium( VI) from simulated seawater
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Polypyrrole modified Fe0-loaded graphene oxide for the enrichment of uranium( VI) from simulated seawater

机译:聚吡咯改性Fe0加载的石墨烯氧化物,用于富含模拟海水的铀(VI)的富集

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摘要

Extraction of uranium(vi) from seawater has attracted much attention for its potential use in the nuclear energy field. In this work, we synthesized graphene oxide-polypyrrole (GO-PPy) through pyrrole monomer polymerization on graphene oxide (GO) with an aqueous solution at low temperature and prepared reduced graphene oxide-polypyrrole-zero-valent iron (rGO-PPy-Fe-0) composites by chemical deposition. We characterized rGO-PPy-Fe-0 using transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The rGO-PPy-Fe-0 composites were investigated for the removal of uranium from aqueous solution and simulated seawater. The experimental results demonstrated that the rGO-PPy-Fe-0 adsorbent possessed a superior capacity for the adsorption of uranium at mg g(-1) and g g(-1) at the pH value of seawater. The adsorption process conformed to the pseudo-second-order rate equation and the Langmuir isotherm model. Based on X-ray photoelectron spectroscopy (XPS), we revealed the possible adsorption mechanism of uranium onto rGO-PPy-Fe-0, which simulated a prospective potential of the adsorbent in seawater.
机译:来自海水的铀(VI)的提取引起了核能领域潜在使用的巨大关注。在这项工作中,通过在低温下用吡咯单体聚合用吡咯单体聚合合成石墨烯 - 聚吡咯(GO-PPY),并在低温下用水溶液制备氧化石墨烯 - 聚吡咯 - 零型铁(RGO-PPY-FE) -0)通过化学沉积复合材料。我们使用透射电子显微镜(TEM),傅里叶变换红外光谱(FTIR)和X射线衍射(XRD)来表征RGO-PPY-FE-0。研究了rgo-ppy-Fe-0复合材料以从水溶液和模拟海水中除去铀。实验结果表明,RGO-PPY-Fe-0吸附剂具有在海水的pH值下以Mg G(-1)和G(-1)的铀吸附的优异能力。吸附过程符合伪二阶率方程和朗米尔等温模型。基于X射线光电子能谱(XPS),我们揭示了铀在RGO-PPY-Fe-0上的可能吸附机制,其在海水中模拟了吸附剂的前瞻性潜力。

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    Harbin Engn Univ Key Lab Superlight Mat &

    Surface Technol Minist Educ Harbin 150001 Heilongjiang Peoples R China;

    Harbin Engn Univ Key Lab Superlight Mat &

    Surface Technol Minist Educ Harbin 150001 Heilongjiang Peoples R China;

    Harbin Engn Univ Key Lab Superlight Mat &

    Surface Technol Minist Educ Harbin 150001 Heilongjiang Peoples R China;

    Harbin Engn Univ Key Lab Superlight Mat &

    Surface Technol Minist Educ Harbin 150001 Heilongjiang Peoples R China;

    Harbin Engn Univ Key Lab Superlight Mat &

    Surface Technol Minist Educ Harbin 150001 Heilongjiang Peoples R China;

    Harbin Engn Univ Key Lab Superlight Mat &

    Surface Technol Minist Educ Harbin 150001 Heilongjiang Peoples R China;

    Harbin Engn Univ Key Lab Superlight Mat &

    Surface Technol Minist Educ Harbin 150001 Heilongjiang Peoples R China;

    Harbin Engn Univ Key Lab Superlight Mat &

    Surface Technol Minist Educ Harbin 150001 Heilongjiang Peoples R China;

    Harbin Engn Univ Key Lab Superlight Mat &

    Surface Technol Minist Educ Harbin 150001 Heilongjiang Peoples R China;

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  • 正文语种 eng
  • 中图分类 化学;无机化学;
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