Novel N-6 trisbidentate ligand coordinated Ir(iii) complexes and their Ru(ii) analogs

Wang Li; Cui Peng; Liu Bingqing; Kilina Svetlana; Sun Wenfang

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Novel N-6 trisbidentate ligand coordinated Ir(iii) complexes and their Ru(ii) analogs

机译：新型N-6三特异性配体配体IR（III）复合物及其Ru（II）类似物

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Novel N-6-coordinated Ir(iii) complexes bearing polypyridyl ligands were synthesized and characterized. In comparison to their Ru(ii) analogs, these Ir(iii) complexes showed blue-shifted UV-vis absorption and emission spectra, but dramatically increased triplet lifetimes with much broader and stronger triplet excited-state absorption.

机译：结合含有聚吡啶配体的新型N-6配位IR（III）复合物被合成并表征。与其Ru（II）类似物相比，这些IR（III）复合物显示出蓝移紫外 - Vis吸收和发射光谱，但大幅增加了具有更广泛和更强的三重态激发 - 状态吸收的三联寿命。

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《Dalton transactions: An international journal of inorganic chemistry》 |2018年第39期|共5页
作者
Wang Li; Cui Peng; Liu Bingqing; Kilina Svetlana; Sun Wenfang;
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作者单位

North Dakota State Univ Dept Chem &

Biochem Fargo ND 58108 USA;

North Dakota State Univ Dept Chem &

Biochem Fargo ND 58108 USA;

North Dakota State Univ Dept Chem &

Biochem Fargo ND 58108 USA;

North Dakota State Univ Dept Chem &

Biochem Fargo ND 58108 USA;

North Dakota State Univ Dept Chem &

Biochem Fargo ND 58108 USA;

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正文语种 eng
中图分类化学;无机化学;
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1. Novel N-6 trisbidentate ligand coordinated Ir(iii) complexes and their Ru(ii) analogs [J] . Wang Li, Cui Peng, Liu Bingqing, Dalton transactions: An international journal of inorganic chemistry . 2018,第39期

机译：新型N-6三特异性配体配体IR（III）复合物及其Ru（II）类似物
2. Effects of trans-pyridine ligands on the interactions of Ru~(II) and Ru~(III) ammine complexes N7-coordinated to purine nucleosides and DNA [J] . Ming Zhao, M. J. Clarke Journal of biological inorganic chemistry: JBIC: a publication of the Society of Biological Inorganic Chemistry . 1999,第3期

机译：反式吡啶配体对Ru〜（II）和Ru〜（III）氨基配合物N7配位与嘌呤核苷和DNA相互作用的影响
3. AMIDE FORMATION FROM ALDIMINE AND WATER PROMOTED BY COORDINATED METAL REDOX - CHEMISTRY OF A FAMILY OF ISOMERIC RU-II(DIIMINE)(2)CL-2, RU-III(DIIMINE)(2)CL-2(+), AND RU-III(DIIMINE)(AMIDE-IMINE)CL-2 COMPLEXES [J] . Menon M., Chakravorty A., Pramanik A. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第12期

机译：配位金属氧化还原过程中由醛丙胺和水形成的酰胺形成-异构RU-II（DIIMINE）（2）CL-2，RU-III（DIIMINE）（2）CL-2（+）和RU- III（二亚胺）（酰胺-亚胺）CL-2配合物
4. Emission properties of Ir(III) complexes with structural change of cyclometalate ligands [C] . WATANABE Kei, OHNO Keiji, NAGASAWA Akira 日本化学会春季年会講演予稿集 . 2018

机译：具有环硫酸盐配体的结构变化的IR（III）复合物的排放性能
5. An investigation of the redox properties and application of Ru (II) and Ir (III) complexes containing multiple metal centers. [D] . Fealy, Ryan J. 2014

机译：含多个金属中心的Ru（II）和Ir（III）配合物的氧化还原性质及其应用的研究。
6. Is macrocycle a synonym for kinetic inertness in Gd(III) complexes? Effect of coordinating and non-coordinating substituents on inertness and relaxivity of Gd(III) chelates with DO3A-like ligands [O] . Miloslav Polasek, Peter Caravan -1

机译：宏观是GD（III）复合物中动力学惰性的同义词吗？配位和非协调取代基对GD（III）螯合物与DO3A样配体的惰性和放松率的影响
7. Facile S-S Bond Activation of Alkyl and Aryl Disulfides by RuCp(CH3CN)3+: Formation of Dinuclear Ru(III)-Ru(III) Complexes with Bridging Thiolate Ligands [O] . -1

机译：通过RUCP（CH3CN）3+的烷基和芳基二硫化芳基的容易S-S键活化：用桥接硫醇酸盐配体形成二核Ru（III）-RU（III）复合物

Novel N-6 trisbidentate ligand coordinated Ir(iii) complexes and their Ru(ii) analogs

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