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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Exploring (bio)catalytic activities of structurally characterised Cu(ii) and Mn(iii) complexes: histidine recognition and photocatalytic application of Cu(ii) complex and derived CuO nano-cubes
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Exploring (bio)catalytic activities of structurally characterised Cu(ii) and Mn(iii) complexes: histidine recognition and photocatalytic application of Cu(ii) complex and derived CuO nano-cubes

机译:结构表征Cu(II)和Mn(III)复合物的探索(生物)催化活性:Cu(II)复合物和衍生CuO纳米立方体的组氨酸识别和光催化施用

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摘要

Structurally characterised two polymeric complexes of Cu(ii) (3) and Mn(iii) (4) of the ligand L (2-(((2-(phenylamino)ethyl)imino)methyl)phenol) have been explored for catecholase-like activity, fluorescence recognition of histidine and catalytic activity towards coupling of aryl iodides with benzamide, leading to N-arylbenzamides. CuO nano-cubes (NCs) prepared by thermal decomposition of the Cu(ii) complex function as photocatalysts for the degradation of methylene blue. Cube-like morphology of CuO nanocrystal and flake-shaped micrometer order Cu(ii) complex have been established from the field emissive scanning electron microscopy (FESEM) images.
机译:已经探讨了合并L((((2-((2-((2-((2-(((2-()((2-(苯基氨基)乙基)亚氨基)甲基)苯酚的甲基)苯酚的两种聚合物复合物)的Cu(II)(3)和Mn(4))。 类似于活性,荧光鉴定组氨酸和催化活性与苯甲酰胺与苯甲酸苯胺偶联,导致N-芳基苯甲酰酰胺。 CuO纳米立方体(NCS)通过Cu(II)的热分解制备的Cu(II)复杂功能作为光催化剂,用于降解亚甲基蓝色。 CuO纳米晶和片状微米阶Cu(II)复合物的立方体样形态已经从场发光扫描电子显微镜(FESEM)图像中建立。

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