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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Optical readout of controlled monomer-dimer self-assembly
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Optical readout of controlled monomer-dimer self-assembly

机译:控制单体二聚体自组装的光学读数

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摘要

5,7-Substituted 1,4-diazepinoporphyrazine magnesium(ii) complexes were synthesized via Mg(ii)-alkoxide templated macrocyclization. A single crystal growth synchrotron diffraction analysis permitted what is to our knowledge the first structural characterization of a 1,4-diazepinoporphyrazine. It exists as a dimer in the solid state. In silico calculations supported by solution phase spectral studies involving a series of representative derivatives, provided insights into the factors governing dimerization of 1,4-diazepinoporphyrazines. The present 1,4-diazepinoporphyrazines serve as useful probes for understanding the determinants that guide dimer-monomer equilibria and the self-assembly of phthalocyanine derivatives.
机译:通过Mg(II)-Alkoxide模板型大环核化合成5,7-取代的1,4-二氮杂卟啉镁(II)配合物。 单晶生长同步rotron衍射分析允许我们了解的是1,4-二氮杂卟啉的第一个结构表征。 它作为固态的二聚体存在。 在涉及一系列代表性衍生物的溶液相谱研究支持的硅计算中,为1,4-二氧管卟啉的二聚化的因子提供了见解。 本发明的1,4-二氮杂卟啉用作理解指导二聚体单体平衡和酞菁衍生物的自组装的决定簇的有用探针。

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