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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Gold nanocatalysts supported on carbon for electrocatalytic oxidation of organic molecules including guanines in DNA
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Gold nanocatalysts supported on carbon for electrocatalytic oxidation of organic molecules including guanines in DNA

机译:金纳催化剂支持碳,用于电催化氧化有机分子,包括DNA的鸟嘌呤

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摘要

Gold (Au) is chemically stable and resistant to oxidation. Although bulk Au is catalytically inert, nanostructured Au exhibits unique size-dependent catalytic activity. When Au nanocatalysts are supported on conductive carbon (denoted as Au@C), Au@C becomes promising for a wide range of electrochemical reactions such as electrooxidation of alcohols and electroreduction of carbon dioxide. In this mini-review, we summarize Au@C nanocatalysts with specific attention on the most recent achievements including the findings in our own laboratories, and show that Au nanoclusters (AuNCs, 2 nm) on nitrided carbon are excellent electrocatalysts for the oxidation of organic molecules including guanines in DNA. The state-of-the-art synthesis and characterization of these nanomaterials are also documented. Synergistic interactions among Au-containing multicomponents on carbon supports and their applications in electrocatalysis are discussed as well. Finally, challenges and future outlook for these emerging and promising nanomaterials are envisaged.
机译:金(Au)是化学稳定和耐氧化。虽然Bulk Au是催化惰性的,但是纳米结构的Au表现出独特的尺寸依赖性催化活性。当Au纳米催化剂在导电碳(表示为Au @ C)上时,Au @ C对于各种电化学反应,例如醇的电氧化和二氧化碳的电氧化物的电化学碳。在这个迷你审查中,我们总结了Au @ c纳催化剂,以特别关注在包括我们自己的实验室中的结果,并表明氮化碳上的Au纳米能器(aunc,&lt 2 nm)是氧化的优异电催化剂在DNA中包括偶胆的有机分子。还记录了这些纳米材料的最先进的合成和表征。还讨论了含含量的碳载体上的含有Au的多组分的协同相互作用及其在电殖分析中的应用。最后,设想了这些挑战和未来前景,这些新兴和有前途的纳米材料是。

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