Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides

Boserle Jiri; Zhigulin Grigory; Ketkov Sergey; Jambor Roman; Ruzicka Ales; Dostal Libor

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Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides

机译：博加工蛋白蛋白蛋白融合的各种反应性朝向有机伪核苷酸

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The reactions of the boraquanidinato germylene (i-Pr)(2)NB(NDmp)(2)Ge (1) (Dmp = 2,6-Me2C6H3) with RN3 and RNCS produced rare examples of Ge2N and Ge3S rings, while the treatment of 1 with RNCO led to an insertion into the N-Ge bond leading to a novel type of germylene stabilized within a six membered ring, i.e. [N(R)C(O)N(Dmp)B(N(i-Pr)(2))N(Dmp)]Ge (R = t-Bu or Ad).

机译：具有RN3和RNC的硼齐氨酰胺常规常氧（I-PR）（2）Nb（2）Nb（NdMP）（2）Ge（DMP = 2,6-Me2C6H3）的反应产生了GE2N和GE3S环的罕见实例，而治疗用RNCO导致插入N-GE键，导致新颖的常规载体稳定在六元环内，即[N（R）C（O）N（DMP）B（N（I-PR）（2））n（dmp）] ge（r = t-bu或AD）。

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《Dalton transactions: An international journal of inorganic chemistry》 |2018年第42期|共4页
作者
Boserle Jiri; Zhigulin Grigory; Ketkov Sergey; Jambor Roman; Ruzicka Ales; Dostal Libor;
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作者单位

Univ Pardubice Fac Chem Technol Dept Gen &

Inorgan Chem Studentska 573 CZ-53210 Pardubice Czech Republic;

RAS GA Razuvaev Inst Organometall Chem 49 Tropinin St Nizhnii Novgorod 603950 Russia;

RAS GA Razuvaev Inst Organometall Chem 49 Tropinin St Nizhnii Novgorod 603950 Russia;

Univ Pardubice Fac Chem Technol Dept Gen &

Inorgan Chem Studentska 573 CZ-53210 Pardubice Czech Republic;

Univ Pardubice Fac Chem Technol Dept Gen &

Inorgan Chem Studentska 573 CZ-53210 Pardubice Czech Republic;

Univ Pardubice Fac Chem Technol Dept Gen &

Inorgan Chem Studentska 573 CZ-53210 Pardubice Czech Republic;

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正文语种 eng
中图分类化学;无机化学;
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1. Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides [J] . Boserle Jiri, Zhigulin Grigory, Ketkov Sergey, Dalton transactions: An international journal of inorganic chemistry . 2018,第42期

机译：博加工蛋白蛋白蛋白融合的各种反应性朝向有机伪核苷酸
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Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides

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