Synthesis, characterization and massspectrometric analysis of [ LSn( IV) F4-x] x+ salts [ L = tris (( 1-ethyl- benzoimidazol-2-yl) methyl) amine, x=1-4]+

Suter Riccardo; Swidan Alaaeddeen; Zijlstra Harmen S.; Macdonald Charles L. B.; McIndoe J. Scott; Burford Neil

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Synthesis, characterization and massspectrometric analysis of [ LSn( IV) F4-x] x+ salts [ L = tris (( 1-ethyl- benzoimidazol-2-yl) methyl) amine, x=1-4]+

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Synthesis, characterization and massspectrometric analysis of [ LSn( IV) F4-x] x+ salts [ L = tris (( 1-ethyl- benzoimidazol-2-yl) methyl) amine, x=1-4]+

机译：[LSN（IV）F4-X] X +盐的合成，表征和质谱分析[L = Tris（（1-乙基 - 苯并咪唑-2-基）甲基）胺，x = 1-4] +

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A series of complexes with the formulae [(BIMEt3)SnF4-x][OTf](x) with x = 1-4 has been synthesized by successive fluoride abstraction from SnF4 with TMSOTf in the presence of the tetradentate nitrogen donor BIMEt3 (tris ((1-ethyl-benzoimidazol-2-yl)methyl)amine). Single crystal X-ray diffraction and heteronuclear NMR spectroscopic analysis provided insight into these new main group cations. Electrospray ionization mass spectrometric analysis on solutions containing the different salts allowed for successful detection of the cations [(BIMEt3)SnF](3+), [(BIMEt3)SnF2](2+) and [(BIMEt3)SnF3](+).

机译：通过在四粒子氮供体Bimet3（Tris（Tris（Tris（Tris（Tris（Tris）存在下，通过连续的氟化物抽取（TRIS（（1-乙基苯并咪唑-2-基）甲基）胺）。单晶X射线衍射和异核NMR光谱分析提供了对这些新的主要组阳离子的洞察力。电喷雾电离质谱分析含有不同盐的溶液，其成功检测阳离子[（BiMet3）SnF]（3+），[（BiMet3）SnF2]（2+）和[（Bimet3）SnF3]（+）。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2018年第46期|共8页
作者
Suter Riccardo; Swidan Alaaeddeen; Zijlstra Harmen S.; Macdonald Charles L. B.; McIndoe J. Scott; Burford Neil;
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Univ Victoria Dept Chem Victoria BC V8W 3V6 Canada;

Univ Windsor Dept Chem &

Biochem Windsor ON N9B 3P4 Canada;

Univ Victoria Dept Chem Victoria BC V8W 3V6 Canada;

Univ Windsor Dept Chem &

Biochem Windsor ON N9B 3P4 Canada;

Univ Victoria Dept Chem Victoria BC V8W 3V6 Canada;

Univ Victoria Dept Chem Victoria BC V8W 3V6 Canada;

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正文语种 eng
中图分类化学;无机化学;
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机译：[LSN（IV）F4-X] X +盐的合成，表征和质谱分析[L = Tris（（1-乙基 - 苯并咪唑-2-基）甲基）胺，x = 1-4] +
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Synthesis, characterization and massspectrometric analysis of [ LSn( IV) F4-x] x+ salts [ L = tris (( 1-ethyl- benzoimidazol-2-yl) methyl) amine, x=1-4]+

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