...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Pyrolysis of metal-organic framework (CuBTC) decorated filter paper as a low-cost and highly active catalyst for the reduction of 4-nitrophenol
【24h】

Pyrolysis of metal-organic framework (CuBTC) decorated filter paper as a low-cost and highly active catalyst for the reduction of 4-nitrophenol

机译：金属有机框架（CubTC）的热解装饰滤纸作为低成本和高活性催化剂，用于减少4-硝基苯酚

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The fabrication of noble metal free catalysts with excellent performance and high stability by a simple, efficient, general and low-cost approach remains an urgent task for solving the problem of resource shortage. Herein, Cu-based metal organic frameworks (MOFs) immobilized on commercial filter papers were used as pyrolysis precursors to synthesize CuxO@C at various calcination temperatures. Notably, the resultant CuxO@C-400 exhibits an excellent catalytic performance toward the reaction of reducing 4-nitrophenol (4-NP) to 4-aminophenol (4-AP). By virtue of the large specific surface area, well-developed porosity, good stability and high dispersity of CuxO nanoparticles, the obtained CuxO@C-400 could complete the reduction reaction within 11 min with a large apparent rate constant kappa(app) value (4.8 x 10(-3) s(-1)). Our strategy therefore opens a new avenue for the preparation of low-cost and high-performance noble metal free catalysts.
机译：通过简单，高效，一般和低成本的方法制造具有优异性能和高稳定性的贵金属无金属催化剂仍然是解决资源短缺问题的迫切任务。 这里，固定在商业过滤纸上的Cu基金属有机框架（MOF）用作在各种煅烧温度下合成咖啡锌的热解前体。 值得注意的是，所得的Cuxo @ C-400在将4-硝基苯酚（4-NP）至4-氨基苯酚（4-AP）的反应中表现出优异的催化性能。 凭借大的比表面积，良好的孔隙率，良好的稳定性和源性纳米颗粒的高分散性，所得的Cuxo @ C-400可以在11分钟内完成还原反应，具有大的表观速率常数Kappa（APP）值（ 4.8 x 10（-3）s（-1））。 因此，我们的战略开辟了一种新的途径，用于制备低成本和高性能贵金属无金属游离催化剂。

著录项

  • 来源
  • 作者

    Zhi Lihua; Liu Hua; Xu Youyuan; Hu Dongcheng; Yao Xiaoqiang; Liu Jiacheng;

  • 作者单位

    Northwest Normal Univ Coll Chem &

    Chem Engn Key Lab Polymer Mat Gansu Prov Key Lab Ecoenvironm Related Polymer Mat Minist Ed Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem &

    Chem Engn Key Lab Polymer Mat Gansu Prov Key Lab Ecoenvironm Related Polymer Mat Minist Ed Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem &

    Chem Engn Key Lab Polymer Mat Gansu Prov Key Lab Ecoenvironm Related Polymer Mat Minist Ed Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem &

    Chem Engn Key Lab Polymer Mat Gansu Prov Key Lab Ecoenvironm Related Polymer Mat Minist Ed Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem &

    Chem Engn Key Lab Polymer Mat Gansu Prov Key Lab Ecoenvironm Related Polymer Mat Minist Ed Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem &

    Chem Engn Key Lab Polymer Mat Gansu Prov Key Lab Ecoenvironm Related Polymer Mat Minist Ed Lanzhou 730070 Gansu Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;无机化学;
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号