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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Comment on: 'Synthesis of dodecamolybdoantimonate(v) salts containing the Keggin structure' by Raj P. Singh, Radheshyam P. Khatri, Jean Dubois, Sushma S. Gaur and Mitsuo Abe, J-Chem. Soc., Dalton Trans., 1990, 947-951
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Comment on: 'Synthesis of dodecamolybdoantimonate(v) salts containing the Keggin structure' by Raj P. Singh, Radheshyam P. Khatri, Jean Dubois, Sushma S. Gaur and Mitsuo Abe, J-Chem. Soc., Dalton Trans., 1990, 947-951

机译:评论:“含有Keggin结构的十二次聚酰胺衍生(V)盐的合成”由RAJ P. Singh,Radheshyam P.Khatri,Jean Dubois,Sushma S. Gaur和Mitsuo Abe,J-Chem。 Soc。,道尔顿跨。,1990,947-951

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摘要

The existence of a dodecamolybdoantimonate(v) anion with the Keggin structure would be a highlight of the heteropolyoxometalate chemistry as a whole. However, we could not confirm the existence of ammonium, potassium, rubidium and cesium dodecamolybdoantimonate as claimed by the authors. As a matter of fact, the authors misinterpreted their presented experimental data. Instead of the dodecamolybdoantimonates, the well-known hexagonal molybdenum oxide was prepared. The given misinformation has to be corrected, even 28 years after its publication.
机译:与Keggin结构的十二烷钼二锑酸酯(v)阴离子的存在将是整个杂氧酸盐化学的亮点。 然而,我们无法确认作者所申请的铵,钾,铷和铯十二烷钼酸锰酸酯。 事实上,作者误解了他们所提出的实验数据。 制备了众所周知的六方钼氧化物而不是十二烷钼二铵化合物。 必须纠正给定的错误信息,甚至在出版后28年。

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