Good isomerization of 2-cyclohexenol by two Ru(ii) complexes, synthesis and characterization of a reaction intermediate

Scalambra Franco; Lopez-Sanchez Belen; Romerosa Antonio

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Good isomerization of 2-cyclohexenol by two Ru(ii) complexes, synthesis and characterization of a reaction intermediate

机译：两种ru（ii）复合物，合成和表征反应中间体的良好异构化良好的2-环己烯醇

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The catalytic activities of [RuClCp(PTA)(2)] (1) and [RuCp(PTA)(2)(H2O-O)]OTf (2) were assessed for the redox isomerization of the cyclic allylic alcohol 2-cyclohexenol into cyclohexanone in water and biphasic media. Complex 2 showed unprecedented good TONs for the studied conversion both in water (TON = 647) and in the biphase of cyclohexene/H2O (TON = 3420) while 1 showed a lower but also good activity (water TON = 95, biphasic TON = 100). The catalytic reaction intermediate [RuCp(PTA)(2)((2)-C6H9OH)]CF3SO3 (3) was synthesized and characterized using NMR.

机译：评估[RUCLCP（PTA）（2）]（1）和[RUCP（PTA）（2）（2）（H2O-O）] OTF（2）的催化活性用于环状烯丙基醇2-环己烯醇的氧化还原异构化在水和双相介质中环己酮。复合物2显示出在水（吨= 647）和环己烯/ H2O（吨= 3420）的研究中进行的前所未有的转化吨，而1显示较低但也是良好的活性（水Ton = 95，双相吨= 100 ）。合成催化反应中间体[RUCP（PTA）（2）（（2）-C6H9OH）] CF 3 SO 3（3），并使用NMR表征。

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《Dalton transactions: An international journal of inorganic chemistry》 |2018年第46期|共6页
作者
Scalambra Franco; Lopez-Sanchez Belen; Romerosa Antonio;
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Univ Almeria Fac Ciencias Area Quim Inorgan CIESOL Almeria Spain;

Univ Almeria Fac Ciencias Area Quim Inorgan CIESOL Almeria Spain;

Univ Almeria Fac Ciencias Area Quim Inorgan CIESOL Almeria Spain;

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正文语种 eng
中图分类化学;无机化学;
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1. Good isomerization of 2-cyclohexenol by two Ru(ii) complexes, synthesis and characterization of a reaction intermediate [J] . Scalambra Franco, Lopez-Sanchez Belen, Romerosa Antonio Dalton transactions: An international journal of inorganic chemistry . 2018,第46期

机译：两种ru（ii）复合物，合成和表征反应中间体的良好异构化良好的2-环己烯醇
2. Paramagnetic Ru(III) complexes of tridentate ligands: Characterization of useful intermediates for heteroleptic Ru(II) complexes [J] . Marie-Pierre Santoni, Amlan K. Pal, Garry S. Hanan Inorganic Chemistry Communications . 2011,第2期

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3. TRANSITION-METAL COMPLEXES WITH SULFUR LIGANDS .112. SYNTHESIS AND CHARACTERIZATION OF RUTHENIUM COMPLEXES WITH [RUPS2N2] CORES - SUBSTITUTION, REDOX, AND ACID-BASE REACTIONS OF [RU-II(L)(PR(3))(S2N2H2)] (L=CO, PPR3, R=PR OR CY) AND FIVE-COORDINATE [ [J] . Sellmann D., Knoch F., Moll M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第19期

机译：含硫液体的过渡金属配合物.112。具有[RUPS2N2]孔的钌配合物的合成和表征-[RU-II（L）（PR（3））（S2N2H2）]的取代，氧化还原和酸碱反应（L = CO，PPR3，R = PR或CY）和五坐标[
4. Solid-Liquid Reaction Synthesis and Characterization of Bioinorganic Complexes of Nicotinic Acid with Antimony(III) and Bismuth(III) Ion [C] . Guoqing Zhong, Mei Gu, Yan Zhang International Conference on Material Engineering, Chemistry, Bioinformatics . 2011

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6. Photochemistry of RuII 44′-Bi-123-triazolyl (btz) Complexes: Crystallographic Characterization of the Photoreactive Ligand-Loss Intermediate trans-Ru(bpy)(κ2-btz)(κ1-btz)(NCMe)2+ [O] . Christine E Welby, Georgina K Armitage, Harry Bartley, -1

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机译：Ru（ii）-N-杂环卡宾络合物：合成，表征，转移氢化反应和生物学测定
8. Kinetics and mechanisms of the reactions of alkyl radicals with oxygen and with complexes of Co(III), Ru(III), and Ni(III). [R] . Kelley, D. 1990

机译：烷基与氧以及与Co（III），Ru（III）和Ni（III）的络合物反应的动力学和机理。

Good isomerization of 2-cyclohexenol by two Ru(ii) complexes, synthesis and characterization of a reaction intermediate

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