Fe(II)-Complexation of tripodal hexapeptide ligands with three bidentate triazolylpyridines: induction of metal-centred chirality by peptide macrocyclization

Kobayashi Yuka; Kameda Tomoshi; Hoshino Masaru; Fujii Nobutaka; Ohno Hiroaki; Oishi Shinya

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Fe(II)-Complexation of tripodal hexapeptide ligands with three bidentate triazolylpyridines: induction of metal-centred chirality by peptide macrocyclization

机译：Fe（II） - 三季肽配体与三个二齿三唑基吡啶的复用剂：肽致癌致癌金属中心性胆量

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摘要

Fe(II)-Coordinating peptides, having three bidentate 2-(1,2,3-triazol-4-yl) pyridine moieties at their side-chains, were designed based on the naturally occurring siderophore structures. The C-3-symmetric macrocyclic peptide and an open-chain congener with the same sequence formed Fe(II)-peptide complexes with opposite metal-centred chiralities.

机译：基于天然存在的纵横结构，设计了在其侧链上具有三个二齿2-（1,2,3-三唑-4-基）吡啶部分的Fe（II）的肽。 C-3-对称的大环肽和具有相同序列的开锁同学形成Fe（II） - 具有相对的金属依心性手性的肽复合物。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2017年第40期|共4页
作者
Kobayashi Yuka; Kameda Tomoshi; Hoshino Masaru; Fujii Nobutaka; Ohno Hiroaki; Oishi Shinya;
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作者单位

Kyoto Univ Grad Sch Pharmaceut Sci Sakyo Ku Kyoto 6068501 Japan;

Natl Inst Adv Ind Sci &

Technol Artificial Intelligence Res Ctr Koutou Ku 2-4-7 Aomi Tokyo 1350064 Japan;

Kyoto Univ Grad Sch Pharmaceut Sci Sakyo Ku Kyoto 6068501 Japan;

Kyoto Univ Grad Sch Pharmaceut Sci Sakyo Ku Kyoto 6068501 Japan;

Kyoto Univ Grad Sch Pharmaceut Sci Sakyo Ku Kyoto 6068501 Japan;

Kyoto Univ Grad Sch Pharmaceut Sci Sakyo Ku Kyoto 6068501 Japan;

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正文语种 eng
中图分类化学;无机化学;
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1. Fe(II)-Complexation of tripodal hexapeptide ligands with three bidentate triazolylpyridines: induction of metal-centred chirality by peptide macrocyclization [J] . Kobayashi Yuka, Kameda Tomoshi, Hoshino Masaru, Dalton transactions: An international journal of inorganic chemistry . 2017,第40期

机译：Fe（II） - 三季肽配体与三个二齿三唑基吡啶的复用剂：肽致癌致癌金属中心性胆量
2. Asymmetric induction and configurational stability at the metal centre in half-sandwich (eta(6)-p-Cymene)ruthenium(II) and (eta(5)-C5Me5)rhodium(III) complexes containing chiral N-N* ligands with different rigidity and flexibility [J] . Saporita M, Bottari G, Brancatelli G, European journal of inorganic chemistry . 2008,第1期

机译：半三明治（eta（6）-p-Cymene）钌（II）和（eta（5）-C5Me5）铑（III）络合物的金属中心的不对称感应和构型稳定性，这些配合物具有不同的刚性和手性NN *配体灵活性
3. Asymmetric induction and configurational stability at the metal centre in half-sandwich (eta(6)-p-Cymene)ruthenium(II) and (eta(5)-C5Me5)rhodium(III) complexes containing chiral N-N* ligands with different rigidity and flexibility [J] . Saporita M, Bottari G, Brancatelli G, European journal of inorganic chemistry . 2008,第1期

机译：半三明治（eta（6）-p-Cymene）钌（II）和（eta（5）-C5Me5）铑（III）络合物的金属中心的不对称感应和构型稳定性，这些配合物具有不同的刚性和手性NN *配体灵活性
4. A novel rigid bidentate B/P ligand:Formation of a formally Ir(III) η~6-benzene complex [C] . Falk William Seidel, Kyoko Nozaki 日本化学会春季年会 . 2020

机译：一种新型刚性二齿B / P配体：形成纯IR（III）η〜6-苯络合物的形成
5. Synthesis of the chiral pentadentate oxoferryl complex and its function in the enantioselective oxidation of peptides and the synthesis and characterization of the chiral cobalt(III) complex. [D] . Hammoud, Mirvat. 2009

机译：手性五齿草酸酯配合物的合成及其在肽的对映选择性氧化中的作用以及手性钴（III）配合物的合成和表征。
6. Crystal structures of three mercury(II) complexes HgCl2L where L is a bidentate chiral imine ligand [O] . Guadalupe Hernández, Sylvain Bernès, Oscar Portillo, 2015

机译：三种汞（II）配合物HgCl2L其中L是双齿手性亚胺配体
7. Stereospecific control of the metal-centred chirality of rhodium(III) and iridium(III) complexes bearing tetradentate CNN′P ligands [O] . Carmona, María, Rodríguez, Ricardo, Méndez, Isabel, 2017

机译：立体定向控制带有四齿CNN'P配体的铑（III）和铱（III）配合物的金属中心手性

Fe(II)-Complexation of tripodal hexapeptide ligands with three bidentate triazolylpyridines: induction of metal-centred chirality by peptide macrocyclization

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