Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex

Whited Matthew T.; Zhang Jia; Ma Senjie; Nguyen Binh D.; Janzen Daron E.

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Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex

机译：含硅甲硅烷辅助氢化物转移到CO 2和CS2，在[P2SI] RU钳型复合物

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The synthesis and characterization of base-stabilized and base-free pincer-type bis(phosphine)/silylene [P2Si]Ru complexes are reported. The base-free complex readily reduces CO2 and CS2 via silylene-assisted hydride transfer, affording structurally distinct products with silicon-to-ruthenium formate and dithioformate bridges.

机译：据报道了碱稳定的碱稳定和磷酸甲硅烷烯型[P2SI] Ru复合物的合成和表征。无基质复合物易于通过甲硅烷醚辅助氢化物转移减少CO 2和CS2，得到结构上不同的产品，其具有硅 - 钌甲酸酯和二氧化碳桥。

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第43期|共5页
作者
Whited Matthew T.; Zhang Jia; Ma Senjie; Nguyen Binh D.; Janzen Daron E.;
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Carleton Coll Dept Chem Northfield MN 55057 USA;

Carleton Coll Dept Chem Northfield MN 55057 USA;

Carleton Coll Dept Chem Northfield MN 55057 USA;

Carleton Coll Dept Chem Northfield MN 55057 USA;

St Catherine Univ Dept Chem &

Biochem St Paul MN 55105 USA;

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正文语种 eng
中图分类化学;无机化学;
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1. Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex [J] . Whited Matthew T., Zhang Jia, Ma Senjie, Dalton transactions: An international journal of inorganic chemistry . 2017,第43期

机译：含硅甲硅烷辅助氢化物转移到CO 2和CS2，在[P2SI] RU钳型复合物
2. Insertion reactions of heteroallenes (CS2 and CO2) into the Ru-H bond of Cp ' Ru(PTA)(PR3)H complexes (PTA=1,3,5-triaza-7-phosphaadamantane) [J] . Lanorio Jocelyn P., Frost Brian J. Inorganica Chimica Acta . 2019,第期

机译：杂丙烯（Cs2和CO2）的插入反应到CP'RU（PTA）（PR3）H络合物的Ru-H键（PTA = 1,3,5-三氮氧磺酰胺）
3. Intramolecular N-H...H-Ru proton-hydride interaction in ruthenium complexes with (2-(dimethylamino)ethyl)cyclopentadienyl and (3-(dimethylamino)propyl)cyclopentadienyl ligands. Hydrogenation of CO2 to formic acid via the N-H...H-Ru hydrogen-bonded co [J] . Chu HS., Wong KY., Wong WT., Organometallics . 1998,第13期

机译：钌与（2-（二甲基氨基）乙基）环戊二烯基和（3-（二甲基氨基）丙基）环戊二烯基配体的钌配合物中的分子内N-H ... H-Ru质子-氢化物相互作用。通过N-H ... H-Ru氢键合钴将CO2加氢成甲酸
4. Metal-ligand Cooperative Reaction of Alkenes on an Iridium Complex Bearing a Pincer-type Alkoxy Carbene Ligand [C] . Kohei Takahashi, Nobuharu Iwasawa 日本化学会春季年会講演予稿集 . 2018

机译：烯烃在铱络合物上含有钳型烷氧基Carbene配体的金属 - 配体的合作反应
5. I. Stereochemistry of cyclopropane formation involving group (IV) organometallic complexes. II. Slower stoichiometric and faster catalytic reduction of aldehydes by the PPh(3) substituted hydroxycyclopentadienyl ruthenium hydride [2,5-Ph(2)-3,4-Tol(2)(eta(5)-C(4)COH)]Ru(CO)(PPh(3))H: A highly chemoselective catalyst for hydrogenation of aldehydes over ketones. [D] . Strotman, Neil Adham. 2005

机译：I.涉及（IV）族有机金属配合物的环丙烷形成的立体化学。二。由PPh（3）取代的羟基环戊二烯基氢化钌[2,5-Ph（2）-3,4-Tol（2）（eta（5）-C（4）COH）] Ru的化学计量较慢和较快的醛催化还原（CO）（PPh（3））H：一种高度化学选择性的催化剂，用于醛在酮上的氢化。
6. An Ab Initio Investigation of the Geometries and Binding Strengths of Tetrel- Pnictogen- and Chalcogen-Bonded Complexes of CO2 N2O and CS2 with Simple Lewis Bases: Some Generalizations [O] . Ibon Alkorta, Anthony C. Legon 2018

机译：具有简单Lewis碱的CO2N2O和CS2的Tetrel光子原和硫属元素结合的络合物的几何形状和结合强度的从头算研究：一些概化
7. (n6-arene)Ru(bis-NHC) complexes for the reduction of CO2 to formate with hydrogen and by transfer hydrogenation with iPrOH [O] . Sanz Sergio, Azua Barrios Arturo, Peris Fajarnés Eduardo 2010

机译：（n6-arene）Ru（bis-NHC）配合物用于将氢气还原为甲酸盐并通过iprOH转移氢化
8. Oxidation State Properties of Delocalized, Ligand-Bridged Metal Complexes. (Ru3O(CH3CO2)6L3)n+ and the Pyrazine-Bridged, Cluster-Cluster Dimer, (Ru3O(CH3CO2)6(py)2)2pyzm+. [R] . Wilson, S. T., Bondurant, R. F., Meyer, T. J., 1975

机译：离域，配体桥联金属配合物的氧化态特性。（Ru 3 O（CH 3 CO 2）6 L 3）n +和吡嗪桥联，簇 - 簇二聚体，（Ru 3 O（CH 3 CO 2）6（py）2）2pyzm +。

Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex

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