Unexpected formation of a mu-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru-3(CO)(12) and its catalytic activity in carbene transfer reactions

Kroitor Andrey P.; Cailler Lucie P.; Martynov Alexander G.; Gorbunova Yulia G.; Tsivadze Aslan Yu.; Sorokin Alexander B.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Unexpected formation of a mu-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru-3(CO)(12) and its catalytic activity in carbene transfer reactions

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Unexpected formation of a mu-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru-3(CO)(12) and its catalytic activity in carbene transfer reactions

机译：在用Ru-3（CO）（12）的酞菁金属化物质期间，在酞菁的金属化物质中形成穆卡比甲醛（IV）复合物及其催化活性在卡宾转移反应中的催化活性

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A mu-carbido diruthenium( IV) phthalocyanine complex was prepared for the first time from the free-base octabutoxyphthalocyanine by direct metalation with Ru-3(CO)(12). The first examples of the catalytic activity of Ru(IV) binuclear phthalocyanines were demonstrated by the cyclopropanation of aromatic olefins and carbene insertion into the N-H bonds of aromatic or aliphatic amines with turnover numbers of 680-1000 and 580-1000, respectively.

机译：通过用Ru-3（CO）（12）直接金属化，首次从自由基八面丁苯酞菁制备穆碳糖丁烯（IV）酞菁配合物。通过芳族烯烃的环丙烷和卡贝替胺的环丙烷和脂族胺的N-H键分别具有680-1000和580-1000的芳族或脂族胺的N-H键，证明了Ru（IV）双核邻酞菁的第一个实施例。

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第45期|共5页
作者
Kroitor Andrey P.; Cailler Lucie P.; Martynov Alexander G.; Gorbunova Yulia G.; Tsivadze Aslan Yu.; Sorokin Alexander B.;
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作者单位

Moscow MV Lomonosov State Univ Chem Dept Leninskie Gory 1 Bldg 3 GSP 1 Moscow 119991 Russia;

Univ Lyon 1 Inst Rech Catalyse &

Environm Lyon IRCELYON UMR 5256 CNRS 2 Ave A Einstein F-69626 Villeurbanne France;

Russian Acad Sci AN Frumkin Inst Phys Chem &

Electrochem Leninskii Pr 31 Bldg 4 Moscow 119071 Russia;

Russian Acad Sci AN Frumkin Inst Phys Chem &

Electrochem Leninskii Pr 31 Bldg 4 Moscow 119071 Russia;

Russian Acad Sci AN Frumkin Inst Phys Chem &

Electrochem Leninskii Pr 31 Bldg 4 Moscow 119071 Russia;

Univ Lyon 1 Inst Rech Catalyse &

Environm Lyon IRCELYON UMR 5256 CNRS 2 Ave A Einstein F-69626 Villeurbanne France;

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正文语种 eng
中图分类化学;无机化学;
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1. Unexpected formation of a mu-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru-3(CO)(12) and its catalytic activity in carbene transfer reactions [J] . Kroitor Andrey P., Cailler Lucie P., Martynov Alexander G., Dalton transactions: An international journal of inorganic chemistry . 2017,第45期

机译：在用Ru-3（CO）（12）的酞菁金属化物质期间，在酞菁的金属化物质中形成穆卡比甲醛（IV）复合物及其催化活性在卡宾转移反应中的催化活性
2. Reactivity of the uranium(IV) carbene complex [U(BIPM~(TMS))(Cl)(μ-Cl)_2Li(THF)_2] (BIPM~(TMS) = {C(PPh_2NSiMe_3)_2}) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C–F bond activation, and [2 + 2]-cycloaddition reactions [J] . Oliver J. Cooper, David P. Mills, William Lewis, Dalton transactions: An international journal of inorganic chemistry . 2014,第38期

机译：铀（IV）卡宾络合物[U（BIPM〜（TMS））（Cl）（μ-Cl）_2Li（THF）_2]（BIPM〜（TMS）= {C（PPh_2NSiMe_3）_2}）对羰基和杂丙二烯底物：金属维蒂希，加合物形成，CF键活化和[2 + 2]-环加成反应
3. Site-directed anchoring of an N-heterocyclic carbene on a dimetal platform: Evaluation of a pair of diruthenium(i) catalysts for carbene-transfer reactions from ethyl diazoacetate [J] . Saha B., Ghatak T., Sinha A., Organometallics . 2011,第7期

机译：N-杂环卡宾在双金属平台上的定点锚固：评估重氮乙基乙酸乙酯进行卡宾转移反应的一对钌（i）催化剂
4. Catalytic Asymmetric Carbene Transfer Reaction of Diazo Oxime Ethers with Olefines [C] . Linh Da Ho, Kazutaka Shibatomi, Seiji Iwasa 日本化学会春季年会講演予稿集 . 2018

机译：二聚胺肟醚的催化不对称切菜转移反应烯烃
5. EARLY TRANSITION METAL ORGANOMETALLIC REACTIVITY. CATALYTIC ACETYLENE HYDROGENATION AND DIMERIZATION, CARBENE MIGRATORY INSERTION REACTIONS [D] . THRELKEL, RICHARD SCOTT 1980

机译：过渡金属的早期反应活性。催化乙炔加氢和二聚化，碳迁移插入反应
6. Bis(imino)pyridine iron complexes for catalytic carbene transfer reactions [O] . Ban Wang, Isaac G. Howard, Jackson W. Pope, 2019

机译：双（亚氨基）吡啶铁配合物用于催化卡宾转移反应
7. Unexpected formation of a mu-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru-3(CO)(12) and its catalytic activity in carbene transfer reactions [O] . Kroitor, A., Cailler, L., Martynov, A., 2017

机译：酞菁与Ru-3（CO）（12）的金属化过程中mu-carbido diruthenium（IV）配合物的意外形成及其在卡宾转移反应中的催化活性

Unexpected formation of a mu-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru-3(CO)(12) and its catalytic activity in carbene transfer reactions

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