Environmentally benign dry-gel conversions of Zr-based UiO metal-organic frameworks with high yield and the possibility of solvent re-use

Goekpinar Serkan; Diment Tatyana; Janiak Christoph

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Environmentally benign dry-gel conversions of Zr-based UiO metal-organic frameworks with high yield and the possibility of solvent re-use

机译：Zr基UIO金属 - 有机骨架的环境良性干凝胶转化具有高产量和溶剂再使用的可能性

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Herein we report an alternative synthesis method for Zr-based UiO metal-organic frameworks (MOFs), namely dry-gel conversion (DGC). It was possible to synthesize nano-to microsized UiO-66, UiO-66-NH2 and UiO-67 with high crystallinity, high surface area and increased yield using only one-sixth or less of the solvent volume compared to the solution synthesis on the same scale. Additionally, it is shown that solvent re-use is possible over at least five synthesis runs making the DGC method an ecological and extremely solvent-economical route to obtain Zr-based UiO-MOFs with reproducible results.

机译：在此，我们报告了一种替代的Zr基UIO金属 - 有机骨架（MOF）的合成方法，即干凝胶转化（DGC）。与溶液合成相比，可以合成具有高结晶度，高表面积，高度表面积，高表面积，高度的溶剂体积的溶剂体积增加的纳米至微晶UIO-66，UIO-66-NH2和UIO-67。相同的规模。另外，显示在使DGC方法的至少五种合成运行中可以进行生态和极其溶剂 - 经济途径，以获得具有可再现结果的生态和极其溶剂的经济途径，可以进行溶剂再使用。

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第30期|共6页
作者
Goekpinar Serkan; Diment Tatyana; Janiak Christoph;
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正文语种 eng
中图分类化学;无机化学;
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1. Environmentally benign dry-gel conversions of Zr-based UiO metal-organic frameworks with high yield and the possibility of solvent re-use [J] . Goekpinar Serkan, Diment Tatyana, Janiak Christoph Dalton transactions: An international journal of inorganic chemistry . 2017,第30期

机译：Zr基UIO金属 - 有机骨架的环境良性干凝胶转化具有高产量和溶剂再使用的可能性
2. One-pot di- and polysaccharides conversion to highly selective 2,5-dimethylfuran over Cu-Pd/Amino-functionalized Zr-based metal-organic framework (UiO-66(NH2))@SGO tandem catalyst [J] . Insyani Rizki, Verma Deepak, Cahyadi Handi Setiadi, Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications . 2019,第期

机译：通过Cu-Pd /氨基官能化Zr基金属骨架（UIO-66（NH2））@ Sge串联催化剂对高选择性的2,5-二甲基呋喃转化为高选择性的2,5-二甲基呋喃（UIO-66（NH2））
3. Spherical Sandwich Au@Pd@UIO-67/Pt@UIO-n (n=66, 67, 69) Core-Shell Catalysts: Zr-Based Metal-Organic Frameworks for Effectively Regulating the Reverse Water-Gas Shift Reaction [J] . Xu Haitao, Luo Xikuo, Wang Jiajia, ACS applied materials & interfaces . 2019,第22期

机译：球形夹层AU @ PD @ UIO-67 / PT @ UIO-N（n = 66,67,69）核 - 壳催化剂：基于Zr的金属 - 有机框架，用于有效调节反向水煤气变换反应
4. Ethene Dimerization over Zr-Based Metal-Organic Framework (UiO-67) Functionalized with Ni and Bipyridine [C] . Mustafa Komurcu, Andrea Lazzarini, Gurpreet Kaur Natural Gas Conversion Symposium . 2019

机译：用Ni和Biphyridine官能化的Zr基金属骨架（UIO-67）乙烯二聚化
5. Catalytic Behavior of Metal-Organic Framework UiO-66 in Conversion of Saccharide Biomass [D] . Morales, Ricardo Daniel 2018

机译：金属有机骨架UiO-66对糖类生物质转化的催化行为
6. An Efficient Synthesis Strategy for Metal-Organic Frameworks: Dry-Gel Synthesis of MOF-74 Framework with High Yield and Improved Performance [O] . Atanu Kumar Das, Rama Sesha Vemuri, Igor Kutnyakov, -1

机译：金属-有机骨架的有效合成策略：高产率和改进性能的干凝胶合成MOF-74骨架
7. Incorporation of cisplatin into the metal-organic frameworks UiO66-NH2 and UiO66 – encapsulation vs. conjugation. [O] . Mocniak, Katarzyna Anna, Kubajewska, Ilona, Spillane, Dominic E.M., 2015

机译：将顺铂结合到金属有机骨架UiO66-NH2和UiO66中-封装与共轭。

Environmentally benign dry-gel conversions of Zr-based UiO metal-organic frameworks with high yield and the possibility of solvent re-use

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