Structural and reactivity insights into covalently linked Cu(I) complex-Anderson polyoxometalates

Schoenweiz S.; Sorsche D.; Schwarz B.; Rau S.; Streb C.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Structural and reactivity insights into covalently linked Cu(I) complex-Anderson polyoxometalates

【24h】

Structural and reactivity insights into covalently linked Cu(I) complex-Anderson polyoxometalates

机译：结构和反应性见解共价连接的Cu（I）复合物 - 安德森聚氧酸盐

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The synthesis, crystallographic analysis and full characterization of the Cu(I) complex-functionalized Anderson polyoxomolybdate anions ((Bu4N)-Bu-n)[MMo6O18((OCH2)(3)CNCH(C47H37N2P2OCu)(2))] (M = Mn3+, Fe3+, Co3+) is reported. For the first time, direct crystallographic evidence for the covalent attachment of a photoactive metal complex to an organo-functionalized polyoxometalate is obtained. Initial electrochemical and photochemical studies report fundamental properties and solution stability of the compounds.

机译：Cu（I）Cu（I）复合官能化的Anderson聚氧钼酰胺阴离子（（Bu4N）-Bu-N）[MMO6O18（（（OCH2）（3）CNCH（C47H37N2P2P2OCU）（2））]的合成，结晶分析及全部表征报道了Mn3 +，Fe3 +，Co3 +）。首次，获得用于将光活性金属络合物的共价连接到有机官能化的聚氧酸盐的直接结晶证据。初始电化学和光化学研究报告了化合物的基本性质和解决方案稳定性。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2017年第30期|共5页
作者
Schoenweiz S.; Sorsche D.; Schwarz B.; Rau S.; Streb C.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Structural and reactivity insights into covalently linked Cu(I) complex-Anderson polyoxometalates [J] . Schoenweiz S., Sorsche D., Schwarz B., Dalton transactions: An international journal of inorganic chemistry . 2017,第30期

机译：结构和反应性见解共价连接的Cu（I）复合物 - 安德森聚氧酸盐
2. Synthesis and structural characterization of lanthanide complexes with the di- or tri-anionic diguanidinate ligand: new insight into the flexibility and distinct reactivity of the linked diguanidinate ligand [J] . Chengfu Pi, Zhenyu Zhu, Linhong Weng, Chemical Communications . 2007,第21期

机译：带有二或三阴离子双胍基配体的镧系元素配合物的合成和结构表征：对连接的双胍基配体的灵活性和独特反应性的新见解
3. Mixed-ligand Cu(II)-containing coordination polymer based on V-shape carboxylate and pyridinyl co-linkers: structural insights, molecular docking and anti-breast cancer activity evolution [J] . Nie Gang, Mao Yan, Lv Zhidong, Journal of Experimental Nanoscience . 2019,第1期

机译：基于V形羧酸盐和吡啶基副联机的混合配体Cu（II） - 统一性聚合物：结构见解，分子对接和抗乳腺癌活动进化
4. Hybrid Polymers Containing Covalently Linked Polyoxometalates [C] . Zhonghua Peng, Jeonghee Kang, Meng Lu PMSE Symposia . 2006

机译：含有共价连接的聚氧酸盐的杂化聚合物
5. Synthesis and characterization of covalently-linked dendrimer bioconjugates and the non-covalent self-assembly of streptavidin-based megamers. [D] . McLean, Megan E. 2004

机译：共价连接的树状聚合物生物共轭物的合成和表征以及链霉亲和素基大分子单体的非共价自组装。
6. Towards Covalent Photosensitizer-Polyoxometalate Dyads-Bipyridyl-Functionalized Polyoxometalates and Their Transition Metal Complexes [O] . Andreas Winter, Patrick Endres, Erik Schröter, 2019

机译：迈向共价光敏剂-多金属氧酸盐二联体-联吡啶官能化的多金属氧酸盐及其过渡金属配合物
7. Mixed-ligand Cu(II)-containing coordination polymer based on V-shape carboxylate and pyridinyl co-linkers: structural insights, molecular docking and anti-breast cancer activity evolution [O] . Gang Nie, Yan Mao, Zhidong Lv, 2019

机译：基于V形羧酸盐和吡啶基副联机的混合 - 配体Cu（II）配位聚合物：结构见解，分子对接和抗乳腺癌活动进化

Structural and reactivity insights into covalently linked Cu(I) complex-Anderson polyoxometalates

摘要

著录项

相似文献

相关主题

期刊订阅