Formation of a spiro compound via coupling of a cyclopentadienyl ligand with a diene moiety of titanacyclopentadiene

Bando Masayoshi; Mizukami Yuki; Nakajima Kiyohiko; Song Zhiyi; Takahashi Tamotsu

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Formation of a spiro compound via coupling of a cyclopentadienyl ligand with a diene moiety of titanacyclopentadiene

【24h】

Formation of a spiro compound via coupling of a cyclopentadienyl ligand with a diene moiety of titanacyclopentadiene

机译：通过与二纳环戊二烯的二烯部分的环戊二烯基配体偶联形成螺螺旋化合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The treatment of titanacyclopentadienes with bismuth(III) chloride gave spiro compounds in moderate yields. Two carbon atoms of the diene moiety of the titanacyclopentadiene were connected to one carbon atom of the Cp ligand. This is in sharp contrast to the formation of dihydroindene derivatives, where two carbon-carbon bonds were formed between the diene moiety and the adjacent two carbon atoms of the Cp ligand.

机译：用氯化铋（III）氯化铋的钛环环戊二烯治疗使螺螺旋化合物适中的产率。二纳环戊二烯的二烯部分的两个碳原子连接到CP配体的一个碳原子。这与二羟基茚衍生物的形成鲜明对比，其中在二烯部分和CP配体的相邻两个碳原子之间形成两个碳 - 碳键。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2017年第47期|共4页
作者
Bando Masayoshi; Mizukami Yuki; Nakajima Kiyohiko; Song Zhiyi; Takahashi Tamotsu;
展开▼
作者单位

Hokkaido Univ Inst Catalysis Sapporo Hokkaido 0010021 Japan;

Hokkaido Univ Inst Catalysis Sapporo Hokkaido 0010021 Japan;

Aichi Univ Educ Dept Chem Kariya Aichi 4488542 Japan;

Hokkaido Univ Inst Catalysis Sapporo Hokkaido 0010021 Japan;

Hokkaido Univ Inst Catalysis Sapporo Hokkaido 0010021 Japan;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Formation of a spiro compound via coupling of a cyclopentadienyl ligand with a diene moiety of titanacyclopentadiene [J] . Bando Masayoshi, Mizukami Yuki, Nakajima Kiyohiko, Dalton transactions: An international journal of inorganic chemistry . 2017,第47期

机译：通过与二纳环戊二烯的二烯部分的环戊二烯基配体偶联形成螺螺旋化合物
2. Ring transformations of heterocyclic compounds. XXIV [1]. 1 ',2 ', 5 ',6 '-tetrahydro-4 ' H-spiro[cyclohexa-2,4-diene-1,2 '-pyrrolo[3,2,1-ij]quinoline] and 1,2,4,5,6,7-hexahydrospiro[azepino[3,2,1-hi]indole-2,1 '-cyclo-hexa[2,4]diene] - Two new spiro [J] . Zimmermann T Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 2004,第5期

机译：杂环化合物的环转化。二十四[1]。 1'，2'，5'，6'-四氢-4'H-螺[环己-2,4-二烯-1,2'-吡咯并[3,2,1-ij]喹啉]和1,2， 4,5,6,7-六氢螺[azepino [3,2,1-hi]吲哚-2,1'-环-六[2,4]二烯]-两个新的螺
3. Regio- and stereoselective ring-opening reactions of chiral substituted spiro[2.4]hepta-4,6-dienes: A new, simple, and versatile approach to the synthesis of optically active bidentate cyclopentadienyl-phosphine ligands. X-ray crystal structure of (S [J] . Ciruelos S., Salzer A., Bolm C., Organometallics . 2000,第12期

机译：手性取代的螺[2.4]庚-4,6-二烯的区域和立体选择性开环反应：一种合成光学活性双齿环戊二烯基膦配体的新颖，简单且通用的方法。（S的X射线晶体结构
4. Ni(0)-Catalyzed Coupling Reaction of 1,3-Diene and Carbonyl Compound Using N-Heterocyclic Carbene as a Ligand [C] . Rieko Sawaki, Yoshihiro Sato, Miwako Mori Symposium on Organometallic Chemistry . 2003

机译：Ni（0） - 使用N-杂环碳化物作为配体的1,3-二烯和羰基化合物的催化反应
5. New designs of rigid pincer ligands (PNP and PCP) and their transition metal complexes in the context of formation of M=C (M-carbene) moiety, strong bond activation (carbon-hydrogen, nitrogen-carbon, carbon-chloride) and catalysis [D] . Weng, Wei 2006

机译：刚性钳位配体（PNP和PCP）及其过渡金属络合物在M = C（M-卡宾）部分形成，强键活化（碳-氢，氮-碳，氯化碳）和催化作用下的新设计
6. Intermolecular Metal-Catalyzed Reductive Coupling of Dienes Allenes and Enynes with Carbonyl Compounds and Imines [O] . Michael Holmes, Leyah A. Schwartz, Michael J. Krische -1

机译：分子间金属催化的二烯丙二烯和烯炔与羰基化合物和亚胺的还原偶联
7. The cyclopentadienyl-osmium moiety as template for the formation of a dihydronaphthylphosphine by coupling between phenylacetylene and an α-alkenylphosphine [O] . Baya Miguel, Buil María L., Esteruelas Miguel A., 2013

机译：环戊二烯基-部分作为模板，通过苯基乙炔与α-烯基膦的偶合形成二氢萘基膦

Formation of a spiro compound via coupling of a cyclopentadienyl ligand with a diene moiety of titanacyclopentadiene

摘要

著录项

相似文献

相关主题

期刊订阅