A novel 2-D Mn selenidostannate(IV) incorporating high-nuclear Mn clusters with spin canting behavior

Zhou Jian; Xiao Hong; Zou Hua-Hong; Liu Xing

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A novel 2-D Mn selenidostannate(IV) incorporating high-nuclear Mn clusters with spin canting behavior

机译：一种新的2-D Mn SeleniDostannate（iv），其具有旋转倾抗行为的高核Mn簇

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A solvothermal reaction of SnCl4 center dot 5H(2)O, Mn and Se in ethanolamine (Hea) yielded a novel 2-D Mn selenidostannate(IV) [Mn-7(ea)(6)(SnSe4)(2)](n) (1), which not only provides the first example of the incorporation of a hepta-nuclear Mn cluster [Mn-7(ea)(6)](8+) into a selenidostannate(IV) framework, but also shows unusual spin canting behavior.

机译：SnCl4中心点5h（2）O，Mn和Se在乙醇胺（HEA）中的溶剂热反应产生了一种新的2-D Mn SeleniDOrdann酸盐（IV）[Mn-7（EA）（6）（SNSE4）（2）]（ n）（1），不仅提供了将庚氏核Mn簇[Mn-7（ea）（6）]（8 +）掺入硒化诱导（iv）框架的第一个例子，还显示出不寻常的自旋倾倒行为。

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第46期|共5页
作者
Zhou Jian; Xiao Hong; Zou Hua-Hong; Liu Xing;
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Chongqing Normal Univ Coll Chem Chongqing Key Lab Inorgan Funct Mat Chongqing 401331 Peoples R China;

Chongqing Normal Univ Coll Chem Chongqing Key Lab Inorgan Funct Mat Chongqing 401331 Peoples R China;

Guangxi Normal Univ State Key Lab Chem &

Mol Engn Med Resources Sch Pharm &

Chem Guilin 541004 Peoples R China;

Chongqing Normal Univ Coll Chem Chongqing Key Lab Inorgan Funct Mat Chongqing 401331 Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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1. A novel 2-D Mn selenidostannate(IV) incorporating high-nuclear Mn clusters with spin canting behavior [J] . Zhou Jian, Xiao Hong, Zou Hua-Hong, Dalton transactions: An international journal of inorganic chemistry . 2017,第46期

机译：一种新的2-D Mn SeleniDostannate（iv），其具有旋转倾抗行为的高核Mn簇
2. Two Metal-Organic Frameworks Based on Hexanuclear Cobalt-Hydroxyl Clusters or a Manganese-Hydroxyl Chain from Triangular [M-3(II)(mu(3)-OH)] (M = Co and Mn) Units: Antiferromagnetic and Spin-Canting Antiferromagnetic Ordering with Soft-Magnetic Behavior [J] . Zhou Lei, Zhao Manzhu, Zhang Xiaoying, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2020,第17期

机译：基于六核钴 - 羟基簇的两种金属 - 有机框架或来自三角形的锰 - 羟基链[M-3（ii）（mu（3）-OH）]（m = Co和Mn）单元：反铁磁性和旋倾荷具有软磁行为的反铁磁性排序
3. From tetranuclear cluster with single-molecule-magnet behavior to 1D alternating spin-canting chain in a Fe(III)-Mn(III) bimetallic system [J] . Ji-Xiang Hu, Yan-Juan Zhang, Yang Xu Inorganic Chemistry Communications . 2014,第Null期

机译：从单分子磁体行为的四核簇到Fe（III）-Mn（III）双金属系统中的一维交替自旋倾斜链
4. Evolution of magnetic properties and canted spin behavior of the La{sub}(0.7-x)Pr{sub}xPb{sub}0.3MnO{sub}3 manganite [C] . Lance Horng, S. L. Young IEEE International Magnetics Conference . 2005

机译：La {sub}（0.7-x）Pr {sub} xpb {sub} 0.3mno {sub} 3锰的磁性和倾斜旋转行为的演变和倾斜旋转行为
5. The structure and reactivity of a series of high-valent oxo complexes of Ru and Mn: Ru(III)-mediated catalytic oxygenation of triphenylphosphine, characterization of binuclear Mn(III,III) and Mn(III,IV) dimers, and mononuclear iron(III) and iron(IV). [D] . Fackler, Nathanael L. P. 1997

机译：Ru和Mn的一系列高价羰基配合物的结构和反应性：Ru（III）介导的三苯膦催化氧化，双核Mn（III，III）和Mn（III，IV）二聚体的表征以及单核铁（III）和铁（IV）。
6. Incorporation of μ3-CO3 into an MnIII/MnIV Mn12 cluster: {(cyclam)MnIV(μ-O)2MnIII(H2O)(μ-OH)6(μ3-CO3)2}Cl8·24H2O [O] . Ben B. Levaton, Marilyn M. Olmstead 2010

机译：将μ3-CO3掺入MnIII / MnIV Mn12团簇中：{（（cyclam）MnIV（μ-O）2MnIII（H2O）（μ-OH） 6（μ3-CO3）2} Cl8·24H2O
7. Two MetalOrganic Frameworks Based on Hexanuclear CobaltHydroxyl Clusters or a ManganeseHydroxyl Chain from Triangular MII3(3OH) (M = Co and Mn) Units: Antiferromagnetic and Spin-Canting Antiferromagnetic Ordering with Soft-Magnetic Behavior [O] . -1

机译：基于六核钴硫基簇的两个金属有机骨架或来自三角形MII3（3OH）（M = CO和Mn）单位的锰羟基链：具有软磁性行为的反铁磁性和旋涂反铁磁性排序

A novel 2-D Mn selenidostannate(IV) incorporating high-nuclear Mn clusters with spin canting behavior

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