Syntheses, structures and properties of metal phosphates Pb2Mg(PO4)(2), Pb4Zn8(PO4)(8) and alpha-BaZn2(PO4)(2)

Pan Xiaobo; Wen Ming; He Guijie; Li Hongyi; Jia Dianzeng

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Syntheses, structures and properties of metal phosphates Pb2Mg(PO4)(2), Pb4Zn8(PO4)(8) and alpha-BaZn2(PO4)(2)

机译：金属磷酸盐Pb2mg（PO4）（2），PB4ZN8（PO4）（8）和α-BAZN2（PO4）（2）的合成，结构和性质

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Pb2Mg(PO4)(2), Pb4Zn8(PO4)(8) and alpha-BaZn2(PO4)(2) have been synthesized by the standard solid-state reaction and their structures were determined by single crystal X-ray diffraction for the first time. Pb2Mg(PO4)(2), Pb4Zn8(PO4)(8) and alpha-BaZn2(PO4)(2) crystallize in the monoclinic crystal system, P2(1)/c, C2/c and the trigonal crystal system, P (3) over bar m1, respectively. The structure of Pb2Mg(PO4)(2) possesses a three-dimensional framework consisting of MgO6 octahedra and PO4 tetrahedra and the Pb2+ cations reside in the [Mg6P6O12] tunnels. Pb4Zn8(PO4)(8) and alpha-BaZn2(PO4)(2) are two-dimensional layered structures with [Zn4P4O16](infinity) layers for Pb4Zn8(PO4)(8) and [Zn3P3O12](infinity) honeycomb double layers for alpha-BaZn2(PO4)(2). And in the structure of Pb4Zn8(PO4)(8), there are four different Zn-P-O layers, which is reported for the first time in zinc phosphates. In addition, thermal property analysis, and UV-Vis-NIR diffuse reflectance and infrared spectroscopy were also performed. First-principles theoretical studies were also conducted to aid the understanding of their band structures and densities of states.

机译：Pb2Mg（PO 4）（2），Pb4Zn8（PO 4）（8）和α-BaZn2（PO 4）（2）已通过标准的固相反应法合成并通过单晶X射线衍射对于第一确定了它们的结构时间。 Pb2Mg（PO 4）（2），Pb4Zn8（PO 4）（8）和α-BaZn2（PO 4）在单斜晶系（2）结晶，P2（1）/ C，C2 / c与三方晶系，P（ 3）在分别杆M1，。 Pb2Mg（PO 4）（2）的结构具有一个由MgO6八面体和四面体PO4和Pb2 +的阳离子的三维骨架驻留在[Mg6P6O12]隧道。 Pb4Zn8（PO 4）（8）和α-BaZn2（PO 4）（2）与[Zn4P4O16]（无穷大），用于Pb4Zn8（PO 4）（8）和[Zn3P3O12]层（无穷大）蜂窝双层二维层状结构的α-BaZn2（PO 4）（2）。和在Pb4Zn8（PO 4）（8）的结构中，有四个不同的Zn-P-O层，其报道了在磷酸锌的第一次。此外，热性能分析，和紫外 - 可见 - 近红外漫反射和红外光谱也进行。还进行了第一性原理的理论研究，以帮助他们能带结构和态密度的了解。

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第46期|共7页
作者
Pan Xiaobo; Wen Ming; He Guijie; Li Hongyi; Jia Dianzeng;
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Xinjiang Univ Inst Appl Chem Key Lab Adv Funct Mat Key Lab Energy Mat Chem Minist Educ Urumqi 830046 Xinjiang Peoples R China;

Harbin Inst Technol Sch Chem &

Chem Engn Harbin 150001 Heilongjiang Peoples R China;

Xinjiang Univ Sch Phys Sci &

Technol Urumqi 830046 Peoples R China;

Xinjiang Prod Qual Supervis &

Inspect Inst Techn Urumqi 830011 Peoples R China;

Xinjiang Univ Inst Appl Chem Key Lab Adv Funct Mat Key Lab Energy Mat Chem Minist Educ Urumqi 830046 Xinjiang Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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1. Syntheses, structures and properties of metal phosphates Pb2Mg(PO4)(2), Pb4Zn8(PO4)(8) and alpha-BaZn2(PO4)(2) [J] . Pan Xiaobo, Wen Ming, He Guijie, Dalton transactions: An international journal of inorganic chemistry . 2017,第46期

机译：金属磷酸盐Pb2mg（PO4）（2），PB4ZN8（PO4）（8）和α-BAZN2（PO4）（2）的合成，结构和性质
2. Syntheses, structures, and ion-exchange properties of the three-dimensional framework uranyl gallium phosphates, Cs-4[(UO2)(2)(GaOH)(2)(PO4)(4)]center dot H2O and Cs[UO2Ga(PO4)(2)] [J] . Shvareva TY, Sullens TA, Shehee TC, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第2期

机译：三维构架的铀酰磷酸镓Cs-4 [（UO2）（2）（GaOH）（2）（PO4）（4）]中心点H2O和Cs [UO2Ga（）的合成，结构和离子交换性能PO4）（2）]
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机译：[M3In（PO4）（2）]（n）（M = K，n = 10; M = Rb，n = 2）化合物的碱金属铟（III）磷酸盐的晶体结构以及能带结构和化学键性质[Rb3In（PO4）（2）]（2）的晶体
4. The First Ammonium Indium(Ⅲ) Phosphates NH4In(OH)PO4, NH4InPO3(OH)2 and(NH4)2InP2O7(OH) with New Types: Syntheses and Structures [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：新类型的第一批磷酸铵铟（NH4In（OH）PO4，NH4In PO3（OH） 2和（NH4）2InP2O7（OH）：合成和结构
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机译：三种新的过渡金属硼磷酸Na5（H3O）{MiI3 B3O3（OH） 3（PO4）6} 2H2O（MII = Mn，Co，Ni）的合成，结构，离子电导率和磁性性质

Syntheses, structures and properties of metal phosphates Pb2Mg(PO4)(2), Pb4Zn8(PO4)(8) and alpha-BaZn2(PO4)(2)

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