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Experimental assessment of the utilization of a novel interpenetrating polymer network in different processes in the agricultural sector

机译:农业部门不同过程中新型互渗聚合物网络利用的实验评估

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We synthesized a biodegradable, controlled release formulation via the impregnation of methyl methacrylic acid onto the natural polysaccharide, gum tragacanth, and a polyacrlyic-based hydrogel with glutaraldehyde as crosslinker. The biodegradation behavior of the prepared interpenetrating polymer network (IPN) was investigated with soil burial and composting methods, and the biodegradability stages were studied with Fourier transform infrared spectroscopy and scanning electron microscopy analyses. The controlled release data of the calcium nitrate was analyzed in accordance with Fick's power law, and the kinetics parameters of the release process were calculated. The values of the initial and lateral diffusion coefficients indicated a fast initial release rate of the fertilizers in comparison to the lateral release. The synthesized IPN was degraded 91.62% within 11 weeks under composting methods, whereas it degraded 78.83% under the soil burial method. The results show that the synthesized IPN was ecofriendly and could be used for the controlled release of agrochemicals. The impact of the degraded IPN on the fertility of the soil was also studied. We concluded from the results obtained that the biodegraded IPN did not have any adverse effects on the soil fertility. Hence, this biodegradable IPN could be of great significance from a green revolution point of view. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47739.
机译:我们通过甲基丙烯酸浸渍到天然多糖,胶葡萄状和与戊二醛作为交联剂的多族水凝胶中合成可生物降解的控释制剂。采用土壤埋葬和堆肥方法研究制备的互持聚合物网络(IPN)的生物降解行为,用傅里叶变换红外光谱和扫描电子显微镜分析研究了生物降解性阶段。根据Ficc的权力法分析硝酸钙的受控释放数据,并计算释放过程的动力学参数。初始和横向扩散系数的值表明与横向释放相比,肥料的快速初始释放速率。在堆肥方法下,合成的IPN在11周内降解了91.62%,而土壤埋葬方法下降78.83%。结果表明,合成的IPN是Ecofriendly的,可用于农业化学物质的控制释放。还研究了降解IPN对土壤肥力的影响。我们从获得的结果中得出结论,生物降解的IPN对土壤肥力没有任何不利影响。因此,这种可生物降解的IPN可能具有来自绿色革命的观点具有重要意义。 (c)2019 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2019,136,4739。

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