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One-step synthesis of hydrophilic graphene-Fe3O4-PVA composite film: Micromorphology and performance

机译:亲水性石墨烯-FE3O4-PVA复合膜的一步合成:微晶和性能

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摘要

Multifunctional polymers have wide applications in smart materials. In this study, the multifunctional polymer (hydrophilic graphene-Fe3O4-PVA, GFP composite films) were synthesized by mixing with hydrophilic graphene (HG), ferrous ammonium sulfate, and ferric chloride in PVA solution through one-pot coprecipitation method. GFP composite films were characterized by XRD, FT-IR. Their morphology and particle size of Fe3O4 in GFP composite film were observed by TEM, SEM, and AFM. The results indicated that the morphology of Fe3O4 in GFP could be modulated from sphere shape to rod structure by the loading quantity of HG. Besides, many properties of GFP composite films were investigated. Firstly, GFP composite films demonstrated the fast magnetic response and high thermal stability. Secondly, the introduction of HG not only simultaneously enhanced the stiffness and ductility of GFP composite films, but also improved their flame retarding performance. Finally, HG regulating effect for the morphology of Fe3O4 in GFP and improvement mechanism of HG for mechanical performance of GFP composite films were illustrated. Both of them might be contributed to the hydrogen bonds effect among Fe3O4, PVA, and HG. Thus, these multifunctional GFP composite films can be applicable as the basis of fabricating smart materials in different fields. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48174.
机译:多功能聚合物在智能材料中具有广泛的应用。在该研究中,通过用单锅共沉淀法在PVA溶液中与PVA溶液中的亲水性石墨烯(Hg),亚铁铵和氯化铁混合来合成多官能聚合物(亲水石墨烯-FE3O4-PVA,GFP复合膜)。 GFP复合薄膜的特征在于XRD,FT-IR。通过TEM,SEM和AFM观察它们在GFP复合膜中FE3O4的形态和粒径。结果表明,通过HG的负载量从球形形状调制GFP中Fe3O4的形态。此外,研究了GFP复合膜的许多性质。首先,GFP复合薄膜证明了快速磁响应和高热稳定性。其次,引入HG不仅同时增强了GFP复合膜的刚度和延展性,而且还提高了它们的阻燃性能。最后,示出了GFP复合薄膜GFP中Fe3O4形态的Hg调节效果及GFP复合膜的机械性能。它们两者可能导致Fe3O4,PVA和Hg之间的氢键效应。因此,这些多功能GFP复合膜可以作为制造不同领域的智能材料的基础。 (c)2019 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2019,136,48174。

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