Use of sustainable glucose and furfural in the synthesis of formaldehyde-free phenolic resole resins

Sui Guanghui; Cheng Yanyan; Yang Xiaomin; Wang Xiaofeng; Wang Zichen

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Use of sustainable glucose and furfural in the synthesis of formaldehyde-free phenolic resole resins

机译：使用可持续葡萄糖和糠醛在合成甲醛酚醛脱氧树脂中

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Sustainable resol-type resins [phenol-furfural-glucose (PFuG), phenol-furfural (PFu), and phenol-glucose resins] were synthesized via alkali catalysis. The chemical structures of the PFuG resins, which had different molar ratios of glucose to furfural, were analyzed by H-1-NMR and Fourier transform infrared spectroscopy. A possible mechanism for formation of the PFuG resin was proposed. The crosslinking curing behaviors of the PFuG resins were examined by differential scanning calorimetry analysis. The performance of the PFuG resins as wood adhesives was studied. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47732.

机译：可持续的溶液型树脂[酚糠醛 - 葡萄糖（pfug），酚类 - 糠醛（PFU）和酚醛树脂]通过碱催化合成。通过H-1-NMR和傅立叶变换红外光谱分析具有不同摩尔葡萄糖葡萄糖的葡萄糖比的PFUG树脂的化学结构。提出了形成Pfug树脂的可能机制。通过差示扫描量热法分析检查PFUG树脂的交联固化行为。研究了Pfug树脂作为木材粘合剂的性能。（c）2019 Wiley期刊，Inc.J.Phill。聚合物。 SCI。 2019,136,47732。

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来源
《Journal of Applied Polymer Science》 |2019年第28期|共5页
作者
Sui Guanghui; Cheng Yanyan; Yang Xiaomin; Wang Xiaofeng; Wang Zichen;
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作者单位

Jilin Univ Coll Chem Changchun 130012 Jilin Peoples R China;

Jilin Univ Coll Chem Changchun 130012 Jilin Peoples R China;

Jilin Univ Coll Chem Changchun 130012 Jilin Peoples R China;

Jilin Univ Coll Chem Changchun 130012 Jilin Peoples R China;

Jilin Univ Coll Chem Changchun 130012 Jilin Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
关键词
addition polymerization; adhesives; biopolymers and renewable polymers; resins; thermal properties;

机译：添加聚合;粘合剂;生物聚合物和可再生聚合物;树脂;热性质;

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1. Use of sustainable glucose and furfural in the synthesis of formaldehyde-free phenolic resole resins [J] . Sui Guanghui, Cheng Yanyan, Yang Xiaomin, Journal of Applied Polymer Science . 2019,第27a28期

机译：使用可持续葡萄糖和糠醛在合成甲醛酚醛脱氧树脂中
2. Microwave-assisted synthesis and characterization of resole-type phenolic resins [J] . Srivastava Kavita, Srivastava Deepak, Tripathi Santosh K. High performance polymers . 2015,第1期

机译：甲阶酚醛树脂的微波辅助合成与表征
3. Synthesis and Properties of Glues for Densified Laminated Wood Based on Alcohol-Soluble Phenol-Cardanol-Formaldehyde Resolic Resins [J] . O. F. Shishlov, D. P. Troshin, N. S. Baulina, Polymer science. Series D . 2015,第1期

机译：醇溶性酚-腰果酚-甲醛树脂的致密层压木材胶的合成及性能
4. THE SYNTHESIS AND PYROLYSIS MECHANISM OF RESOLE PHENOLIC RESIN FOR ABLATIVE MATERIALS [C] . Dawei Han, Hu Honglin, Ruilian Yu, International astronautical congress . 2014

机译：烧成材料用酚醛树脂的合成与热解机理
5. Synthesis of phenolic resin amines and solid-state NMR of phenolic resins in NASA rocket motors. [D] . Lu, Jinqi. 1998

机译：NASA火箭发动机中酚醛树脂胺的合成和酚醛树脂的固态NMR。
6. Rheological Study of Phenol Formaldehyde Resole Resin Synthesized for Laminate Application [O] . Nuruldiyanah Kamarudin, Dayang Radiah Awang Biak, Zurina Zainal Abidin, 2020

机译：酚醛醛树脂对层压施用的流变研究
7. Preferred reaction pathways in the base-catalysed synthesis of phenolic resole resins [O] . Price John A. 1980

机译：碱催化酚醛甲酚醛树脂合成中的优选反应途径
8. HPLC Characterization of Phenol-Formaldehyde Resole Resin Used in Fabrication of Shuttle Booster Nozzles [R] . Young, Philip R. 1999

机译：用于制造梭式增压器喷嘴的苯酚 - 甲醛树脂树脂的HpLC表征

Use of sustainable glucose and furfural in the synthesis of formaldehyde-free phenolic resole resins

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