Metal-phenolic networks: A biobased synergist for EVA/APP composites toward enhanced thermal stability and flame retardancy

Hu Zai-Yin; Xu Shimei; Zhao Hai-Bo; Wang Yu-Zhong

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Metal-phenolic networks: A biobased synergist for EVA/APP composites toward enhanced thermal stability and flame retardancy

机译：金属 - 酚醛网络：用于EVA / APP复合材料的生物化协同性，朝向增强的热稳定性和阻燃性

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In the present study, a biomass-derived metal-phenolic networks (MPN) were used as charring agent and flame-retardant synergist for Ethylene-vinyl acetate/Ammonium polyphosphate (EVA/APP) composites. Compared with the polyphenol, the thermal stability of MPN was improved remarkably, making it a good match for EVA. Meanwhile, Limit oxygen index test revealed that MPN endowed EVA/APP composites with enhanced flame-retardant performance. The reason on improvement in the flame retardancy of composites was also discussed and the corresponding mechanism was proposed. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47243.

机译：在本研究中，将生物质衍生的金属 - 酚醛网络（MPN）用作乙烯 - 乙酸乙烯酯/氨基磷酸铵（EVA / APP）复合材料的炭化剂和阻燃协同剂。与多酚相比，MPN的热稳定性显着提高，使其成为EVA的良好匹配。同时，限制氧指数试验显示，MPN赋予了具有增强阻燃性能的EVA / App复合材料。还讨论了改善复合材料阻燃性的原因，并提出了相应的机制。（c）2018 Wiley期刊，Inc.J.Phill。聚合物。 SCI。 2019,136,47243。

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来源
《Journal of Applied Polymer Science》 |2019年第12期|共5页
作者
Hu Zai-Yin; Xu Shimei; Zhao Hai-Bo; Wang Yu-Zhong;
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作者单位

Sichuan Univ Sch Chem Engn Chengdu 610065 Sichuan Peoples R China;

Sichuan Univ Ctr Degradable &

Flame Retardant Polymer Mat Natl Engn Lab Ecofriendly Polymer Mat Sichuan Coll Chem State Key Lab Polymer Mat Engn Chengdu 610065 Sichuan Peoples R China;

Sichuan Univ Ctr Degradable &

Flame Retardant Polymer Mat Natl Engn Lab Ecofriendly Polymer Mat Sichuan Coll Chem State Key Lab Polymer Mat Engn Chengdu 610065 Sichuan Peoples R China;

Sichuan Univ Ctr Degradable &

Flame Retardant Polymer Mat Natl Engn Lab Ecofriendly Polymer Mat Sichuan Coll Chem State Key Lab Polymer Mat Engn Chengdu 610065 Sichuan Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
关键词
charring mechanism; EVA; flame retardant; metal-phenolic networks; thermal stability;

机译：炭化机制;EVA;阻燃剂;金属 - 酚醛网络;热稳定性;

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专利

1. Metal-phenolic networks: A biobased synergist for EVA/APP composites toward enhanced thermal stability and flame retardancy [J] . Hu Zai-Yin, Xu Shimei, Zhao Hai-Bo, Journal of Applied Polymer Science . 2019,第11a12期

机译：金属 - 酚醛网络：用于EVA / APP复合材料的生物化协同性，朝向增强的热稳定性和阻燃性
2. Covalently functionalized graphene oxide wrapped by silicon–nitrogen-containing molecules: preparation and simultaneous enhancement of the thermal stability, flame retardancy and mechanical properties of epoxy resin nanocomposites [J] . Yanlong Sui, Lijie Qu, Peihong Li, RSC Advances . 2020,第24期

机译：通过含硅氮分子包裹的共价官能化的石墨烯：制备和同时增强热稳定性，阻燃性和机械性能的环氧树脂纳米复合材料
3. Thermal exfoliation of hexagonal boron nitride for effective enhancements on thermal stability, flame retardancy and smoke suppression of epoxy resin nanocomposites via sol-gel process [J] . Yu Bin, Xing Weiyi, Guo Wenwen, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2016,第19期

机译：六方氮化硼的热剥落可通过溶胶-凝胶工艺有效增强环氧树脂纳米复合材料的热稳定性，阻燃性和抑烟性
4. Effect of APP-TiO2 on Flame Retardancy and Thermal Stability in EVA/Al(OH)3 Composites [C] . F.Wu, B.Cheng, D.Li, International symposium on flame-retardant materials technologies . 2018

机译：App-TiO2对EVA / Al（OH）3复合材料中的阻燃性和热稳定性的影响
5. Polyethylene-layered double hydroxides and montmorillonite nanocomposites: Thermal, mechanical and flame retardance properties. [D] . Kosuri, Divya. 2008

机译：聚乙烯层状双氢氧化物和蒙脱土纳米复合材料：热，机械和阻燃性能。
6. Highly Efficient Composite Flame Retardants for Improving the Flame Retardancy Thermal Stability Smoke Suppression and Mechanical Properties of EVA [O] . Yilin Liu, Bin Li, Miaojun Xu, 2020

机译：高效复合阻燃剂可提高EVA的阻燃性热稳定性抑烟性和机械性能
7. Covalently functionalized graphene oxide wrapped by silicon–nitrogen-containing molecules: preparation and simultaneous enhancement of the thermal stability, flame retardancy and mechanical properties of epoxy resin nanocomposites [O] . Yanlong Sui, Lijie Qu, Peihong Li, 2020

机译：通过含硅氮分子包裹的共价官能化的石墨烯：制备和同时增强热稳定性，阻燃性和机械性能的环氧树脂纳米复合材料

Metal-phenolic networks: A biobased synergist for EVA/APP composites toward enhanced thermal stability and flame retardancy

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