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Synthesis of antibacterial N-halamine acryl acid copolymers and their application onto cotton

机译:抗菌正卤丙烯酸共聚物的合成及其在棉胶中的应用

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A series of N-halamine copolymers are synthesized by reacting hydantoinylacrylamide (HA) with acrylic acid (AA) in several mole ratios. The synthesized copolymers are characterized by Fourier transform infrared (FTIR) and H-1 NMR and coated onto cotton fabrics. The coated cotton fabrics are rendered antibacterial by chlorinating with dilute household bleach solution. The ultraviolet (UVA) light stabilities of the resulting copolymers on the coated cotton fabrics are investigated; the results show that UVA exposure has minimal effect on the structure of the copolymers but can cause partial loss of the chlorine loading on the coated cotton fabrics. The coated cotton fabrics exhibit excellent antibacterial efficacies achieving inactivations of about six logs of Staphylococcus aureus and Escherichia coli O157:H7 within 1 min of contact time. The cotton fabrics coated with the copolymers would best be employed in disposable fabric applications because of lack of washing fastness due to the weak bonding interaction between the AA unit and cellulose. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47426.
机译:通过在几种摩尔比中与丙烯酸(AA)反应,通过使亚丙烯酸(HA)反应来合成一系列N-卤胺共聚物。合成的共聚物的特征在于傅里叶变换红外(FTIR)和H-1 NMR并涂覆到棉织物上。通过用稀释的家用漂白剂溶液氯化涂覆的棉织物是抗菌。研究了所得共聚物在涂覆的棉织物上的紫外(UVA)光稳定性;结果表明,UVA暴露对共聚物结构具有最小的影响,但可引起涂层棉织物上的氯负载的部分损失。涂层棉织物表现出优异的抗菌效果,在1分钟内达到约6种葡萄球菌和大肠杆菌o157:H7的术语。涂有共聚物的棉织物最好在一次性织物应用中使用,因为由于AA单元和纤维素之间的粘接性弱相互作用而缺乏洗涤牢度。 (c)2018 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2019,136,47426。

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