首页> 外文期刊>Journal of Applied Polymer Science >Effect of polyhydric alcohols on the mechanical and thermal properties, porosities, and air permeabilities of polyurethane-blended films
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Effect of polyhydric alcohols on the mechanical and thermal properties, porosities, and air permeabilities of polyurethane-blended films

机译:多元醇对聚氨酯共混膜的机械和热性能,孔隙率和空气渗透性的影响

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摘要

Polyurethane (PU) and polyhydric alcohols composites were successfully prepared to be used as coating materials for fabrics. The effects of various polyhydric alcohols on the PU composites properties have been investigated. The tensile strengths, glass-transition temperatures, thermal-mechanical properties, and swelling capacities of the PU/polyhydric-alcohol-blended films are described in detail, along with their surface and cross-sectional morphologies. The tensile strengths and glass-transition temperatures of the PU/polyhydric-alcohol-blended films were found to decrease remarkably with increasing polyhydric-alcohol concentration. The swelling capacities and porosities of the PU/poly(propylene glycol) (PPG)-blended and PU/glycerol-blended films were observed to increase with increasing PPG or glycerol concentration. However, the poly(ethylene glycol) (PEG) concentration in the PU/PEG-blended film did not significantly affect its properties. The air and water-vapor permeability of nonwoven nylon fabrics coated with PU/PPG and PU/glycerol increased with increasing PPG or glycerol contents, while those coated with PU/PEG were unaffected by PEG content. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47429.
机译:成功制备聚氨酯(PU)和多元醇复合材料以用作织物的涂料材料。研究了各种多元醇对PU复合材料的影响。详细描述了PU /多元醇共混膜的拉伸强度,玻璃转变温度,热机械性能和溶胀容量以及它们的表面和横截面形态。发现PU /多元醇共混膜的拉伸强度和玻璃化转变温度随着多元醇浓度的增加而显着降低。观察PU / Poly(丙二醇)(PPG) - 配合和PU /甘油共混膜的溶胀容量和孔隙率随着PPG或甘油浓度的增加而增加。然而,PU / PEG共混膜中的聚(乙二醇)(PEG)浓度没有显着影响其性质。涂有PU / PPG和PU /甘油的非织造尼龙织物的空气和水蒸气渗透率随着PPG或甘油含量的增加而增加,而涂有PU / PEG的那些不受PEG含量影响。 (c)2018 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2019,136,47429。

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