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Reusable ionic liquid-functionalized polystyrene for the highly efficient removal of sulfadiazine sodium

机译:可重复使用的离子液体官能化聚苯乙烯,用于高效除去磺胺嘧啶钠

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摘要

The extensive use of sulfonamides has caused serious ecotoxicological effects, sulfonamide antibiotics are difficult to remove when they are in their anionic form. In this work, a novel polystyrene supported ionic liquid (PS-CH2-[TSiIm][Cl]) material was prepared for the effective removal of sulfadiazine sodium (SDS). Results showed that the adsorption efficiency maintained relatively stable and high in a wide pH (6-10) and temperature (25-70 degrees C) ranges. SDS adsorbed onto the PS-CH2-[TSiIm][Cl] could be well evaluated by Langmuir model and the maximum adsorption capacity could be reached as high as 438.2 mgg(-1). Simultaneously, the PS-CH2-[TSiIm][Cl] exhibited excellent removal performance toward trace SDS at ppb level (0.005mgL(-1)). Common inorganic ions such as K+, Na+, Ca2+, and Cl- had no effect of on the removal of SDS even if their concentrations were 20000 times higher than that of SDS. And the PS-CH2-[TSiIm][Cl] was easy to regenerate without loss in adsorption performance. Additionally, the PS-CH2-[TSiIm][Cl] was applied to remove the SDS from environmental water samples. The possible adsorption mechanism was also investigated. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47981.
机译:广泛使用磺胺酰胺导致严重的生态毒理学效应,磺酰胺酰胺抗生素难以在其阴离子形式上移除。在这项工作中,制备了一种新型聚苯乙烯负载的离子液体(PS-CH2- [Tsiim] [Cl])材料,用于有效除去磺胺噻嗪(SDS)。结果表明,吸附效率在宽pH(6-10)和温度(25-70℃)范围内保持相对稳定和高。吸附在PS-CH2- [TSIIM] [CL]上的SDS可以通过Langmuir模型进行很好的评估,并且最大吸附能力可以高达438.2mg(-1)。同时,PS-CH2- [TSIIM] [CL]在PPB水平(0.005mg1))下对痕量SDS表现出优异的去除性能。常见的无机离子,如K +,Na +,Ca 2+和Cl-即使它们的浓度高于SDS的浓度高出20000倍,也没有对SDS的除去的影响。并且PS-CH2- [Tsiim] [Cl]易于再生而不会在吸附性能下损失。另外,施加PS-CH2- [TSIIM] [CL]以从环境水样中除去SDS。还研究了可能的吸附机制。 (c)2019 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2019,136,47981。

著录项

  • 来源
    《Journal of Applied Polymer Science》 |2019年第38期|共8页
  • 作者单位

    Henan Normal Univ Sch Environm Key Lab Yellow River &

    Huai River Water Environm Henan Key Lab Environm Pollut Control Minist Educ Xinxiang 453007 Henan Peoples R China;

    North China Univ Water Resources &

    Elect Power Sch Environm &

    Municipal Engn Zhengzhou 450046 Henan Peoples R China;

    Henan Normal Univ Sch Environm Key Lab Yellow River &

    Huai River Water Environm Henan Key Lab Environm Pollut Control Minist Educ Xinxiang 453007 Henan Peoples R China;

    Henan Normal Univ Sch Environm Key Lab Yellow River &

    Huai River Water Environm Henan Key Lab Environm Pollut Control Minist Educ Xinxiang 453007 Henan Peoples R China;

    Henan Normal Univ Sch Environm Key Lab Yellow River &

    Huai River Water Environm Henan Key Lab Environm Pollut Control Minist Educ Xinxiang 453007 Henan Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 高分子化合物工业(高聚物工业);
  • 关键词

    highly efficient removal; ionic liquid functionalized polymer; recyclable; sulfadiazine sodium antibiotic;

    机译:高效去除;离子液体官能化聚合物;可回收;磺胺嘧啶钠抗生素;

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