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Conductive sizing for improving electrical conductivity of carbon fiber/polyaryl ether ketone/AgNWs composites

机译:用于改善碳纤维/聚芳基醚酮/ AgNWS复合材料的导电性的导电尺寸

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The aim of this work is to enhance the electrical conductivity of PAEK/continuous carbon fiber (CF) composites while maintaining their mechanical properties. A conductive sizing was elaborated by mixing polyetherimide (PEI) with silver nanoplates (AgNpts) in suspension in dichloromethane. An aqueous PEI formulation was used as insulating sizing reference. The presence of AgNpts into the sizing enhances electrical conductivity up to 0.2 S.m(-1) for a silver content similar to 0.2 vol % without any modification of mechanical properties. The influence of conductive sizing on PAEK-AgNWs/CF was observed. For low AgNWs content lower (<1 vol %); the conductive sizing increases the electrical conductivity of the composite by one decade. This result shows that both types of Ag particles participate to the conductive path. For higher AgNWs content, electrical conductivity (200 S.m(-1)) is independent from the AgNpts content: the conductive path is only constituted by AgNWs. Mechanical properties of such composites show that the value of the conservative modulus is almost the same, while the dissipative modulus slightly increases. The global mechanical properties of the composite are preserved despite the addition of the CF, AgNWs, and AgNpts. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47872.
机译:这项工作的目的是提高PAEK /连续碳纤维(CF)复合材料的电导率,同时保持其机械性能。通过将聚醚酰亚胺(PEI)与二氯甲烷中的悬浮液中的银纳米层(末端)混合,通过将聚醚酰亚胺(PEI)混合来阐述导电尺寸。将PEI制剂用作绝缘施胶参考。施胶中的腺体的存在增强了相对于0.2Vol%的银含量的电导率高达0.2 s.m(-1),而无需任何机械性能。观察到导电尺寸对Paek-Agnws / Cf的影响。对于低agnws含量更低(<1 Vol%);导电尺寸将复合材料的电导率提高了一个十年。该结果表明,两种类型的AG粒子都参与导电路径。对于较高的Agnws含量,电导率(200 s.m(-1))独立于agnpts内容:导电路径仅由Agnws构成。这种复合材料的力学性能表明,保守模量的值几乎相同,而耗散模量略有增加。尽管添加了CF,AGNW和agnts,但复合材料的全局力学性能保存。 (c)2019 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2019,136,47872。

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