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Capacitance properties of unipolar pulsed electro‐polymerized PEDOT films

机译:单极脉冲电聚合PEDOT薄膜电容性能

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ABSTRACT > Poly(3,4‐ethylenedioxythiophene) (PEDOT) film has been prepared on conductive carbon paper (CP) substrates by unipolar pulse electrochemical deposition. The effects of different polymerization parameters, including pulse potential and width, deposition frequency, and duty cycle on the capacitance of PEDOT films, were studied by cyclic voltammetry in 0.5 M sulfuric acid solution. The PEDOT‐coated CP electrode was characterized by scanning electron microscopy and Fourier transform infrared spectroscopy to confirm the three‐dimensional porous structure and the presence of <mat:math xmlns:mat="http://www.w3.org/1998/Math/MathML" display="inline" altimg="urn:x-wiley:00218995:media:app46729:app46729-math-0001" xmlns:wiley="http://www.wiley.com/namespaces/wiley/wiley" wiley:location="equation/app46729-math-0001.png"> <mat:msubsup> <mat:mrow> <mat:mtext>ClO</mat:mtext> </mat:mrow> <mat:mrow> <mat:mn>4</mat:mn> </mat:mrow> <mat:mrow> <mat:mi>–</mat:mi> </mat:mrow> </mat:msubsup> </mat:math> dopant ion conjugation during the electro‐polymerization. The results of cyclic voltammetry and galvanostatic charge‐discharge show that the PEDOT electrodes exhibit good specific capacitance of 151.31 F/g, rate performance and stability with a retention rate of 80.25% after 5000 cycles. The thin, lightweight electrode materials show considerable potential for low‐cost, high‐performance energy storage applications. ? 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46729. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”> <title type =“main”>摘录</标题> > poly(3,4-亚乙二氧噻吩)(通过单极脉冲电化学沉积在导电碳纸(CP)基材上制备PEDOT)薄膜。通过0.5M硫酸溶液中的循环伏安法研究了不同聚合参数,包括脉冲电位和宽度,沉积频率和占空比对佩特膜的电容的影响。涂覆电子显微镜和傅里叶变换红外光谱的特征在于扫描涂层CP电极,以确认三维多孔结构和<mat:math xmlns:mat =“http://www.w3.org/1998/数学/ mathml“display =”内联“altimg =”URN:X-Wiley:00218995:媒体:APP46729:APP46729-Math-0001“XMLNS:Wiley =”http://www.wiley.com/namespaces/wiley/wiley “Wiley:Location =”等式/ app46729-math-0001.png“> <mat:msubsup> <mat:mrow> <mat:mtext> clo </ mat:mtext> </ mat:mrow> <may:mrow> <MAT:4 </ MAT:Mn> </ MAT:MROW> <MAT:MROW> <MAT:MI> - </ MAT:MI> </ MAT:MROW> </ MAT:MSUBSUP> </ MAT :在电聚合过程中数学>掺杂剂离子缀合。循环伏安法和电镀电荷 - 放电的结果表明,佩特电极表现出151.31 f / g的良好比电容,速率性能和稳定性,保持率为5000次循环后80.25%。薄,轻质电极材料显示出低成本,高性能储能应用的相当大的潜力。还是2018 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2018 </ b>, 135 </ i>,46729. </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-33581/'>《Journal of Applied Polymer Science》</a> <b style="margin: 0 2px;">|</b><span>2018年第40期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Du Haiyan&option=202" target="_blank" rel="nofollow">Du Haiyan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xiaoxiao&option=202" target="_blank" rel="nofollow">Liu Xiaoxiao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ren Zhe&option=202" target="_blank" rel="nofollow">Ren Zhe;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Huimin&option=202" target="_blank" rel="nofollow">Yang Huimin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Yunlong&option=202" target="_blank" rel="nofollow">Yu Yunlong;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>College of Chemistry and Chemical EngineeringTaiyuan University of TechnologyTaiyuan 030024 China;</p> <p>College of Chemistry and Chemical EngineeringTaiyuan University of TechnologyTaiyuan 030024 China;</p> <p>College of Chemistry and Chemical EngineeringTaiyuan University of TechnologyTaiyuan 030024 China;</p> <p>College of Chemistry and Chemical EngineeringTaiyuan University of TechnologyTaiyuan 030024 China;</p> <p>National Engineering Research Center for BiomaterialsSichuan UniversityChengdu Sichuan 610064 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1821.html" title="高分子化合物工业(高聚物工业)">高分子化合物工业(高聚物工业);</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=unipolar pulse method&option=203" rel="nofollow">unipolar pulse method;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=poly (3&option=203" rel="nofollow">poly (3;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=4‐ethylenedioxythiophene)&option=203" rel="nofollow">4‐ethylenedioxythiophene);</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon paper&option=203" rel="nofollow">carbon paper;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=supercapacitor&option=203" rel="nofollow">supercapacitor;</a> </p> <div class="translation"> 机译:单极脉冲法;聚(3;4-乙二氧基噻吩);碳纸;超级电容器; 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