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首页> 外文期刊>Journal of Applied Polymer Science >Expandable graphite encapsulated by magnesium hydroxide nanosheets as an intumescent flame retardant for rigid polyurethane foams
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Expandable graphite encapsulated by magnesium hydroxide nanosheets as an intumescent flame retardant for rigid polyurethane foams

机译：由氢氧化镁纳米片包封的可膨胀石墨作为刚性聚氨酯泡沫的膨胀阻燃剂

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ABSTRACT > Encapsulation of expandable graphite (EG) particles by organic or inorganic shells has been proved to efficiently enhance the expandability of EG, and thus to improve the flame‐retardant efficiency of EG. In this study, magnesium hydroxide (MH) nanosheets were utilized to fabricate core–shell EG@MH flame‐retardant particles through a heterocoagulation method. It was observed that after the encapsulation by MH nanosheets, the edges of the char residue of the EG layer were sealed after combustion, which contributed to the enhancement of expandability. The expansion volume of EG@MH increased dramatically to 456?mL/g, in contrast to 338?mL/g for pure EG. By incorporating 11.5 wt % of flame‐retardant particles, polyurethane foam containing EG@MH (here PU‐EG@MH) displayed excellent flame retardancy. Compared with the physically mixed sample, PU‐EG+MH, the limiting oxygen index value for the PU‐EG@MH sample increased from 29.8% to 32.6%. Furthermore, the shell of MH nanosheets was beneficial for improving the interfacial adherence between EG and the rigid polyurethane foam (RPUF) matrix, due to the reaction between isocyanate functional groups and MH. The cell structure and storage modulus of PU‐EG@MH were improved. In other words, the shell of MH nanosheets successfully improved the flame‐retardant efficiency and enhanced the interface adhesion between EG and the matrix. ? 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46749. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”> <title type =“main”>抽象</ title> >封装可扩展石墨（例如）粒子已经证明有机或无机壳可有效增强例如可扩张性，从而提高了例如uG的阻燃效率。在该研究中，利用氢氧化镁（MH）纳米晶片通过杂镀法制造核 - 壳核 - 壳壳，例如@ MH阻燃颗粒。观察到，在通过MH纳米片的包封后，在燃烧后，例如层的炭残余物的边缘被密封，这有助于增强可扩张性。例如，MH的膨胀体积急剧增加至456Ωml/ g，与纯度为338μml/ g。通过掺入11.5wt％的阻燃颗粒，含有例如@ MH（这里PU-EG-MH）的聚氨酯泡沫显示出优异的阻燃性。与物理混合样品，PU-EG + MH相比，PU-EG-MH样品的限制氧指数值从29.8％增加到32.6％。此外，由于异氰酸酯官能团和MH之间的反应，MH纳米片的壳有利于改善例如刚性聚氨酯泡沫（RPUF）基质之间的界面粘附性。 PU-EG-MH的细胞结构和储存模量得到改善。换句话说，MH纳米片的壳成功地提高了阻燃效率，增强了例如矩阵之间的界面粘附。还是2018 Wiley期刊，Inc.J.Phill。聚合物。 SCI。 2018 </ b>， 135 </ i>，46749. </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-33581/'>《Journal of Applied Polymer Science》</a> <b style="margin: 0 2px;">|</b><span>2018年第40期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Yintao&option=202" target="_blank" rel="nofollow">Wang Yintao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Feng&option=202" target="_blank" rel="nofollow">Wang Feng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dong Quanxiao&option=202" target="_blank" rel="nofollow">Dong Quanxiao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yuan Wenjing&option=202" target="_blank" rel="nofollow">Yuan Wenjing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Peng&option=202" target="_blank" rel="nofollow">Liu Peng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ding Yanfen&option=202" target="_blank" rel="nofollow">Ding Yanfen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Shimin&option=202" target="_blank" rel="nofollow">Zhang Shimin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Mingshu&option=202" target="_blank" rel="nofollow">Yang Mingshu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zheng Guoqiang&option=202" target="_blank" rel="nofollow">Zheng Guoqiang;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Material Science and EngineeringZhengzhou UniversityZhengzhou 450001 China;</p> <p>Beijing National Laboratory for Molecular Sciences Key Laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of SciencesBeijing 100190 China;</p> <p>College of Materials Science and EngineeringBeijing University of Technology100024 China;</p> <p>Beijing National Laboratory for Molecular Sciences Key Laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of SciencesBeijing 100190 China;</p> <p>Beijing National Laboratory for Molecular Sciences Key Laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of SciencesBeijing 100190 China;</p> <p>Beijing National Laboratory for Molecular Sciences Key Laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of SciencesBeijing 100190 China;</p> <p>Beijing National Laboratory for Molecular Sciences Key Laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of SciencesBeijing 100190 China;</p> <p>Beijing National Laboratory for Molecular Sciences Key Laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of SciencesBeijing 100190 China;</p> <p>School of Material Science and EngineeringZhengzhou UniversityZhengzhou 450001 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1821.html" title="高分子化合物工业（高聚物工业）">高分子化合物工业（高聚物工业）;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=applications&option=203" rel="nofollow">applications;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=degradation&option=203" rel="nofollow">degradation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=flame retardance&option=203" rel="nofollow">flame retardance;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=foams&option=203" rel="nofollow">foams;</a> </p> <div class="translation"> 机译：申请;降解;阻燃性;泡沫; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020588836.html">Expandable 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