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Fabrication and properties of PVDF and PVDF‐HFP microfiltration membranes

机译：PVDF和PVDF-HFP微滤膜的制备和性质

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ABSTRACT > Poly(vinylidene fluoride) (PVDF) and poly(vinylidene fluoride)‐ co ‐hexafluoropropylene (PVDF‐HFP) were used to fabricate porous microfiltration membranes via a thermally induced phase separation (TIPS) method, and dibutyl phthalate (DBP) was used as diluent. The effects of polymer concentration on structure and performance were studied in detail. In addition, the effect of incorporation of hexafluoropropylene (HFP) groups on the membrane was also investigated. The formation mechanism was proposed with the assistance of a phase diagram. The results showed that the incorporation of HFP groups resulted in a lower crystallization temperature ( T <sub> c </sub> ) of the polymer/DBP system. In addition, the porosity, pure water flux, and ink solution flux decreased with increasing polymer concentration. In contrast, the water contact angle, ink rejection ratio, and mechanical properties had an increasing tendency. When the polymer concentration was 30 wt %, the obtained membrane was most suitable for microfiltration. Furthermore, the incorporation of HFP groups improved the properties of the obtained membrane, including better hydrophobicity, mechanical properties, antifouling property, and chemical resistance. ? 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46711. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”> <title type =“main”>摘录</ title> >聚（偏二氟乙烯）（pvdf）和聚（偏二氟乙烯） - CO-I> - 氟丙烯（PVDF-HFP）用于通过热诱导的相分离（提示）方法制造多孔微滤膜，并且使用二丁酯（DBP）作为稀释剂。详细研究了聚合物浓度对结构和性能的影响。此外，还研究了掺入六氟丙烯（HFP）基团对膜上的影响。在相图的帮助下提出了地层机制。结果表明，聚合物/ DBP系统的结晶温度（ T </ i> <亚℃/℃/℃）的结晶温度（<I> T </ Sub>）的掺入。另外，孔隙率，纯净水通量和油墨溶液通量随着聚合物浓度的增加而降低。相反，水接触角，油墨排斥比和机械性能具有越来越大的趋势。当聚合物浓度为30wt％时，所获得的膜最适合微滤。此外，HFP组的掺入改善了所得膜的性质，包括更好的疏水性，机械性能，防污性和耐化学性。还是2018 Wiley期刊，Inc.J.Phill。聚合物。 SCI。 2018 </ b>， 135 </ i>，46711. </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-33581/'>《Journal of Applied Polymer Science》</a> <b style="margin: 0 2px;">|</b><span>2018年第40期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xinya&option=202" target="_blank" rel="nofollow">Wang Xinya;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xiao Changfa&option=202" target="_blank" rel="nofollow">Xiao Changfa;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Hailiang&option=202" target="_blank" rel="nofollow">Liu Hailiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huang Qinglin&option=202" target="_blank" rel="nofollow">Huang Qinglin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fu Hao&option=202" target="_blank" rel="nofollow">Fu Hao;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Separation Membranes and Membrane ProcessesTianjin Polytechnic UniversityNo. 399 Binshui Road Xiqing District Tianjin 300387 People's Republic of China;</p> <p>State Key Laboratory of Separation Membranes and Membrane ProcessesTianjin Polytechnic UniversityNo. 399 Binshui Road Xiqing District Tianjin 300387 People's Republic of China;</p> <p>State Key Laboratory of Separation Membranes and Membrane ProcessesTianjin Polytechnic UniversityNo. 399 Binshui Road Xiqing District Tianjin 300387 People's Republic of China;</p> <p>State Key Laboratory of Separation Membranes and Membrane ProcessesTianjin Polytechnic UniversityNo. 399 Binshui Road Xiqing District Tianjin 300387 People's Republic of China;</p> <p>State Key Laboratory of Separation Membranes and Membrane ProcessesTianjin Polytechnic UniversityNo. 399 Binshui Road Xiqing District Tianjin 300387 People's Republic of China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1821.html" title="高分子化合物工业（高聚物工业）">高分子化合物工业（高聚物工业）;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=applications&option=203" rel="nofollow">applications;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mechanical properties&option=203" rel="nofollow">mechanical properties;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=membranes&option=203" rel="nofollow">membranes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=morphology&option=203" rel="nofollow">morphology;</a> </p> <div class="translation"> 机译：应用;机械性能;膜;形态; 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋晓艳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,宋晓艳</a> <span> <a href="/journal-cn-9222/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 天津化工 </a> </span> <span> . 2021</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_information-recording-materials_thesis/0201281829978.html">锂离子电池用PVDF-HFP涂覆隔膜制备及性能研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周旭苗&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 周旭苗</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴斌&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,吴斌</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李娜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李娜</a> <span> <a 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<div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-17019_thesis/020221751821.html">一种离子液体α-MPyHTfa/PVdF-HFP复合膜的制备及其性能研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=苗睿瑛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 苗睿瑛</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=唐玲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,唐玲</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=方勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,方勇</a> <span> <a href="/conference-cn-17019/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2009年第十五次全国电化学学术会议 </a> <span> <span> . 2009</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316023833.html">面向电致变色器件的 PVDF-HFP基凝胶聚合物电解质的制备及改性研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=方超炎&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 方超炎</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120104106551.html">经由添加有机碱的PVDF-HFP的加速热交联以及使用交联的PVDF-HFP作为OTFT装置的栅极介电材料</a> <b>[P]</b> . <span> 中国专利： CN110997832A </span> <span> . 2020-04-10</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061204162547.html">一种PVDF/PVDF-HFP中空纤维膜的制备方法</a> <b>[P]</b> . <span> 中国专利： CN107913604B </span> <span> . 2020.12.22</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130499902891.html">ACCELERATED THERMAL CROSSLINKING OF PVDF-HFP VIA ADDITION OF ORGANIC BASES, AND THE USAGE OF CROSSLINKED PVDF-HFP AS GATE DIELECTRIC MATERIAL FOR OTFT DEVICES</a> <b>[P]</b> . <span> 外国专利：  US2021135109A1 </span> <span> . 2021-05-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过添加有机碱基加速PVDF-HFP的热交联，以及交联PVDF-HFP作为OTFT器件的栅极介电材料的使用 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130400734737.html">/PVDF-HFP Electrical Heating Textile with Graphene/PVDF-HFP Composite by Various Circuit Pattering Conditions</a> <b>[P]</b> . <span> 外国专利：  KR20200057359A </span> <span> . 2020-05-26</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：电路图样条件的石墨烯/ PVDF-HFP复合材料/ PVDF-HFP电加热织物 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130400753717.html">Accelerated thermal crosslinking of PVDF-HFP through the addition of organic base and use of crosslinked PVDF-HFP as gate dielectric material for OTFT devices</a> <b>[P]</b> . <span> 外国专利：  KR20200038272A </span> <span> . 2020-04-10</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过添加有机碱并使用交联的PVDF-HFP作为OTFT器件的栅极介电材料来加速PVDF-HFP的热交联 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704020588837','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img 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