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The tough microcapsules of acrylic acid–styrene–isoprene–styrene quadrablock copolymer shell via Pickering emulsion technique

机译:通过皮克林乳液技术的丙烯酸 - 苯乙烯 - 异戊二烯 - 苯乙烯Quadrablock共聚物壳的坚韧的微胶囊

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ABSTRACT > Pickering emulsion technique has been demonstrated a simple method to fabricate the microcapsules. However, the resulted microcapsules are often fragile. This limits their applications. Here, we report that the microcapsules with the nanostructured shell of poly(acrylic acid‐ b ‐styrene‐ b ‐isoprene‐ b ‐styrene) (ASIS), which is of high toughness and elasticity, could be fabricated via Pickering emulsions using ASIS nanoparticles as stabilizing particles. The surfactant‐free ASIS latex (with theoretical molecular weight for each block: 1.5k–15k–55k–10k) was synthesized by reversible additional fragmentation transfer (RAFT) emulsion polymerization using amphiphilic macro‐RAFT agent [poly(acrylic acid) <sub>20</sub> ‐ b ‐polystyrene <sub>5</sub> trithiocarbonate] as both reactive surfactant and polymerization mediator. It was found that the ASIS nanoparticles were able to self‐assemble on oil/water interface to stabilize Pickering emulsion of hexadecane in the pH range from 8 to 12. The droplet diameter was finely tuned from 17 to 5 μm by increasing the ASIS particle levels from 0.13 to 12 wt % based on the mass of the ASIS aqueous dispersions. With toluene as a coalescing aid, the capsules with a coherent and nonporous shell were obtained with the dispersed phase volume percentage as high as 50%. The toluene treated capsules were so mechanically strong to survive the utrasonic treatment. ? 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46700. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”> <title type =“main”>抽象</ title> >皮克林乳液技术已经证明了一种简单的方法制造微胶囊。然而,所得到的微胶囊通常是脆弱的。这限制了他们的应用程序。在这里,我们报告,与聚的纳米结构的壳的微胶囊(丙烯酸 - 的 B'/ I> - 苯乙烯 - 的 B'/ I> -isoprene-的 B'/ I> - 苯乙烯) (ASIS)具有高韧性和弹性,可以通过吸塑乳液制成使用ASIS纳米颗粒作为稳定颗粒来制造。使用两亲宏观 - 筏剂的可逆额外的碎片转移(RAFT)乳液聚合来合成表面活性剂ASIS乳胶(具有每个嵌段的理论分子量:1.5K-15K-55K-10K)[聚(丙烯酸)<sub > 20 </ sub> - B </ i> -polystyrene <sub> 5 </ sub>三硫代碳酸酯作为反应性表面活性剂和聚合介质。据发现,所述纳米颗粒ASIS能够油/水界面上自组装,以稳定的pH范围内的十六烷皮克林乳液从8至12的液滴直径为精细通过增加ASIS粒子水平调谐从17至5μm基于ASIS水分散体的质量,从0.13至12wt%。用甲苯作为聚结助剂,使用分散相体积百分比高达50%的分散相体积百分比获得胶囊。甲苯处理的胶囊如此机械强,以存活utrasonic治疗。还是2018 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2018 </ b>, 135 </ i>,46700. </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-33581/'>《Journal of Applied Polymer Science》</a> <b style="margin: 0 2px;">|</b><span>2018年第40期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xia Chunmiao&option=202" target="_blank" rel="nofollow">Xia Chunmiao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Luo Yingwu&option=202" target="_blank" rel="nofollow">Luo Yingwu;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>The State Key Laboratory of Chemical Engineering College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027 China;</p> <p>The State Key Laboratory of Chemical Engineering College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1821.html" title="高分子化合物工业(高聚物工业)">高分子化合物工业(高聚物工业);</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=colloids&option=203" rel="nofollow">colloids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=elastomers&option=203" rel="nofollow">elastomers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=morphology&option=203" rel="nofollow">morphology;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanostructured polymers&option=203" rel="nofollow">nanostructured polymers;</a> </p> <div class="translation"> 机译:胶体;弹性体;形态;纳米结构聚合物; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a 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tuijian_authcolor">,李效玉</a> <span> <a href="/journal-cn-56821/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 现代化工 </a> </span> <span> . 2004</span><span>,第7期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-journal-chinese-universities_thesis/0201231631206.html">包覆Fe2O3超微粒的苯乙烯/丙烯酸/丙烯酸丁酯核-壳型复合共聚物的性能研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈平</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杜惠&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杜惠</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘凤歧&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘凤歧</a> <span> <a href="/journal-cn-10958/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高等学校化学学报 </a> </span> <span> . 1998</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-31748_thesis/02022433314.html">苯乙烯-异戊二烯-苯乙烯(SIS)嵌段共聚物的镍系催化加氢</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱家顺&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱家顺</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=文丽荣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,文丽荣</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈滇宝&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈滇宝</a> <span> <a href="/conference-cn-31748/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2001年全国高分子学术论文报告会 </a> <span> <span> . 2001</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312285167.html">AGETATRP阳离子乳液聚合制备聚(苯乙烯-b-丙烯酸丁酯-b-苯乙烯)三嵌段共聚物胶乳</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王振&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王振</a> <span> . 2015</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201879641.html">具有抗菌性能的含环氧基苯乙烯丙烯酸酯共聚物皮克林乳液及其制备和应用</a> <b>[P]</b> . <span> 中国专利: CN103524656B </span> <span> . 2016.01.13</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120102250290.html">具有抗菌性能的含环氧基苯乙烯丙烯酸酯共聚物皮克林乳液及其制备和应用</a> <b>[P]</b> . <span> 中国专利: CN103524656A </span> <span> . 2014-01-22</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130431537846.html">Oil-in-water emulsion for topical application to keratinic materials comprises a styrene-acrylic acid/alkyl acrylate block copolymer and a water-soluble polyoxyalkylated silicone wetting agent</a> <b>[P]</b> . <span> 外国专利: <!-- 法国专利: --> FR2911500A1 </span> <span> . 2008-07-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:局部施用于角蛋白材料的水包油乳液包含苯乙烯-丙烯酸/丙烯酸烷基酯嵌段共聚物和水溶性聚氧烷基化有机硅润湿剂 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130431537847.html">Cosmetic oil-in-water emulsion for treating keratin materials, e.g. for skin care, contains diblock copolymer, based on styrene, acrylic acid and alkyl acrylate as stabilizer</a> <b>[P]</b> . <span> 外国专利: <!-- 法国专利: --> FR2911499A1 </span> <span> . 2008-07-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:化妆品水包油乳液,用于处理角蛋白材料,例如用于皮肤护理,包含基于苯乙烯,丙烯酸和丙烯酸烷基酯的二嵌段共聚物作为稳定剂 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130462846943.html">Non-PVC plastisol compsn. as e.g. automobile sealant - contains emulsion copolymer of styrene cpd. and (meth)acrylic and-or itaconic acid, with plasticiser and inorganic fillers</a> <b>[P]</b> . <span> 外国专利: <!-- 德国专利: --> DE4034725A1 </span> <span> . 1992-05-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:非PVC增塑溶胶成分。如汽车密封胶-含有苯乙烯的乳液共聚物] cpd。和(甲基)丙烯酸]和/或衣康酸,以及增塑剂和无机填料 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 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