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Poly(vinylidene fluoride)-polyacrylonitrile blend flat-sheet membranes reinforced with carbon nanotubes for wastewater treatment

机译:聚(偏二氟乙烯) - 聚酰胺共混物平板膜用碳纳米管加强,用于废水处理

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摘要

In this reported study, poly(vinylidene fluoride) (PVDF) and polyacrylonitrile (PAN) blend flat-sheet membranes were prepared via a phase-inversion method with various loadings of multiwalled carbon nanotubes. The effects of the carbon nanotubes (CNTs) on the performance and morphology of the PVDF-PAN composites were investigated via tests of the pure water flux and rejection of bovine serum albumin, scanning electron microscopy, atomic force microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and contact angle (CA) analysis. The experimental results demonstrate that the CNTs contributed to the improvement of the flux and hydrophilicity of the membranes. The maximum value of the flux was 398.1L m(-2) h(-1), and the value of CA for the composite membranes was found to be 48 degrees. In addition, the results of the mechanical properties tests illustrate that the brittleness and plasticity of the hybrid membranes were greatly improved by the presence of the CNTs. The flux recovery ratio was maintained at 75%; this demonstrated that the PVDF-PAN membranes enhanced with the CNTs possessed good antifouling performance. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46155.
机译:在该报道的研究中,通过具有多壁碳纳米管的各种载荷的相移法制制备聚(偏二氟乙烯)(PVDF)和聚丙烯腈(PAN)混合物平板膜。通过纯水通量和牛血清白蛋白,扫描电子显微镜,原子力显微镜,傅里叶变换红外光谱,研究了碳纳米管(CNTS)对PVDF-PAN复合材料的性能和形态的影响,傅立叶变换红外光谱,x - 射线衍射,热重分析和接触角(CA)分析。实验结果表明,CNT有助于改善膜的通量和亲水性。通量的最大值为398.1LM(-2)H(-1),发现复合膜的Ca值为48度。此外,机械性能试验的结果说明通过CNT的存在大大提高了杂交膜的脆性和可塑性。磁通回收率保持在75%;这证明了PVDF-PAN膜随着CNT的增强具有良好的防污性能。 (c)2017 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2018,135,46155。

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