Hydrophobic properties of poly(arylene ether)s derived from linear polydimethysiloxanes and decafluorobiphenyl

Lin Xinqi; Li Xuesong; Hao Jinmeng; Zhao Xuan; Wei Yanfeng; Mu Jianxin

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Hydrophobic properties of poly(arylene ether)s derived from linear polydimethysiloxanes and decafluorobiphenyl

机译：聚（亚芳基醚）衍生自线性聚二甲基硅氧烷和癸氟硼苯基的聚（亚芳基醚）疏水性质

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A series of novel poly(arylene ether)s were synthesized with diphenol liner polydimethysiloxanes with different silicon numbers (2OH-PDMS-P; P=2, 6, 10, 12, 16) and decafluorobiphenyl via a two-step nucleophilic substitution polymerization. The chemical structures of the polymers were confirmed by Fourier transform infrared spectrometer, F-19-NMR and H-1-NMR spectra. All the polymers provided outstanding hydrophobic properties, high thermal stability and good solubility. The water contact angle (WCA) first increased and then suddenly decreased with the increasing of silicon numbers in PDMS. The highest WCA about 112 degrees was obtained when silicon numbers was ten. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46187.

机译：通过双核数（2OH-PDMS-P; P = 2,6,10,12,12,16）和二核亲核取代聚合，用不同硅数（2OH-PDMS-P; P = 2,6,10,12,16）和二氟双苯基合成了一系列新的聚（亚芳醚）S。通过傅里叶变换红外光谱仪，F-19-NMR和H-1-NMR光谱证实了聚合物的化学结构。所有聚合物都提供出色的疏水性，高热稳定性和良好的溶解度。水接触角（WCA）首先增加，然后随着PDMS中的硅数突然突然下降。当硅数为十个时，获得了最高WCA约112度。（c）2017 Wiley期刊，Inc.J.Phill。聚合物。 SCI。 2018,135,46187。

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来源
《Journal of Applied Polymer Science》 |2018年第16期|共7页
作者
Lin Xinqi; Li Xuesong; Hao Jinmeng; Zhao Xuan; Wei Yanfeng; Mu Jianxin;
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作者单位

Jilin Univ Coll Chem Engn Res Ctr High Performance Plast Minist Educ Changchun 130012 Jilin Peoples R China;

Jilin Univ Coll Chem Engn Res Ctr High Performance Plast Minist Educ Changchun 130012 Jilin Peoples R China;

Jilin Univ Coll Chem Engn Res Ctr High Performance Plast Minist Educ Changchun 130012 Jilin Peoples R China;

Jilin Univ Coll Chem Engn Res Ctr High Performance Plast Minist Educ Changchun 130012 Jilin Peoples R China;

Jilin Univ Coll Chem Engn Res Ctr High Performance Plast Minist Educ Changchun 130012 Jilin Peoples R China;

Jilin Univ Coll Chem Engn Res Ctr High Performance Plast Minist Educ Changchun 130012 Jilin Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
关键词
applications; copolymers; hydrophilic polymers; membranes; thermal properties;

机译：应用;共聚物;亲水性聚合物;膜;热性能;

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1. Hydrophobic properties of poly(arylene ether)s derived from linear polydimethysiloxanes and decafluorobiphenyl [J] . Lin Xinqi, Li Xuesong, Hao Jinmeng, Journal of Applied Polymer Science . 2018,第15a16期

机译：聚（亚芳基醚）衍生自线性聚二甲基硅氧烷和癸氟硼苯基的聚（亚芳基醚）疏水性质
2. Synthesis and characterization of multiblock partially fluorinated hydrophobic poly(arylene ether sulfone)-hydrophilic disulfonated poly(arylene ether sulfone) copolymers for proton exchange membranes [J] . Chen Y., Rowlett J.R., Lee C.H., Journal of Polymer Science, Part A. Polymer Chemistry . 2013,第10期

机译：质子交换膜用多嵌段部分氟化疏水性聚亚芳基砜-亲水性二磺化聚亚芳基醚共聚物的合成与表征
3. Synthesis and Characterization of Multiblock Copolymers Based on Hydrophilic Disulfonated Poly(arylene ether sulfone) and Hydrophobic Partially Fluorinated Poly(arylene ether ketone) for Fuel Cell Applications [J] . Lee HS, Roy A, Lane O, Journal of Polymer Science, Part A. Polymer Chemistry . 2010,第1期

机译：亲水性二磺酸化聚亚芳基醚砜和疏水性部分氟化聚亚芳基醚酮的嵌段共聚物的合成与表征
4. Synthesis and Characterization of Multiblock Partially Fluorinated Hydrophobic Poly(ether ether ketone) Hydrophilic Disulfonated Poly(arylene ether sulfone) Copolymers for Proton Exchange Membranes [C] . Yu Chen, Chang Hyun Lee, Ozma Lane North American Membrane Society Annual Meeting . 2010

机译：多块部分氟化疏水性聚（醚醚酮）亲水性二磺化聚（亚芳基醚砜）共聚物的合成与表征用于质子交换膜的共聚物
5. Quaternary Ammonium Functionalized Poly(Arylene Ether Sulfone) Copolymer Ionomers: Synthesis, Processing, and Structure-property Relationships [D] . Khan, Wayz. 2019

机译：季铵官能化聚（亚芳基醚砜）共聚物离聚物：合成，加工和结构性质关系
6. Anion Exchange Membranes Obtained from Poly(arylene ether sulfone) Block Copolymers Comprising Hydrophilic and Hydrophobic Segments [O] . Jun Ha Kim, Mohanraj Vinothkannan, Ae Rhan Kim, 2020

机译：从包含亲水和疏水链段的聚（亚芳基醚砜）嵌段共聚物中获得阴离子交换膜
7. Anion Exchange Membranes Obtained from Poly(arylene ether sulfone) Block Copolymers Comprising Hydrophilic and Hydrophobic Segments [O] . Jun Ha Kim, Mohanraj Vinothkannan, Ae Rhan Kim, 2020

机译：由聚（亚芳基醚砜）嵌段共聚物的阴离子交换膜包含亲水和疏水区段

Hydrophobic properties of poly(arylene ether)s derived from linear polydimethysiloxanes and decafluorobiphenyl

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