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Preparation of cellulose-graphene oxide aerogels with N-methyl morpholine-N-oxide as a solvent

机译:用N-甲基吗啉-N-氧化物作为溶剂的纤维素 - 石墨烯氧化物气凝胶的制备

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摘要

Cellulose-graphene oxide (GO) aerogel composites were successfully prepared from cellulose and GO dispersed in N-methyl morpholine-N-oxide monohydrate, a nontoxic and environmentally friendly solvent, after a freeze-drying process. Because of the strong interactions between the numerous oxygen-containing groups located on the surface of GO and the functional groups of the cellulose molecules, the GO monolayers were well dispersed in the three-dimensional porous structure of the cellulose aerogels. With the addition of 10 wt % GO, the swelling ratios and water contents of the composite cellulose-GO aerogels increased from 468 to 706% and from 82.4% to 87.6%, respectively. The corresponding maximum decomposition temperatures also increased from 335 to 353 degrees C with increasing GO content from 0 to 10%; this indicated that the thermal stability of the cellulose-GO aerogels was enhanced. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46152.
机译:在冷冻干燥过程之后,成功地由纤维素制备纤维素 - 石墨烯氧化物(GO)气凝胶复合材料,并在冻干过程中分散在N-甲基吗啉-N-氧化物一水合物中,无毒和环保溶剂。 由于位于去的含有纤维素分子表面的许多含氧基团与纤维素分子的官能团之间的强相互作用之间的相互作用,孔单层均匀地分散在纤维素气凝胶的三维多孔结构中。 随着10wt%的添加,复合纤维素 - 孔凝胶的溶胀比和水含量分别从468增加到706%,分别从82.4%达到87.6%。 相应的最大分解温度也从335升增加到353摄氏度,随着0至10%的增加而增加; 这表明增强了纤维素 - 去气凝胶的热稳定性。 (c)2017 Wiley期刊,Inc.J.Phill。 聚合物。 SCI。 2018,135,46152。

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  • 来源
    《Journal of Applied Polymer Science》 |2018年第16期|共7页
  • 作者单位

    Sch Chem Sch Mat Sci &

    Engn Key Lab Display Mat &

    Photoelect Devices Tianjin 300384 Peoples R China;

    Sch Chem Sch Mat Sci &

    Engn Key Lab Display Mat &

    Photoelect Devices Tianjin 300384 Peoples R China;

    Sch Chem Sch Mat Sci &

    Engn Key Lab Display Mat &

    Photoelect Devices Tianjin 300384 Peoples R China;

    Sch Chem Sch Mat Sci &

    Engn Key Lab Display Mat &

    Photoelect Devices Tianjin 300384 Peoples R China;

    Sch Chem Sch Mat Sci &

    Engn Key Lab Display Mat &

    Photoelect Devices Tianjin 300384 Peoples R China;

    Zhejiang Univ Zhejiang Calif Int Nanosyst Inst Taizhou Branch Hangzhou 310012 Zhejiang Peoples R China;

    Sch Chem Sch Mat Sci &

    Engn Key Lab Display Mat &

    Photoelect Devices Tianjin 300384 Peoples R China;

    Univ Mons Chim Interact Plasma Surface 20 Pl Parc B-7000 Mons Belgium;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 高分子化合物工业(高聚物工业);
  • 关键词

    cellulose and other wood products; gels; graphene and fullerenes; nanotubes;

    机译:纤维素和其他木制品;凝胶;石墨烯和富勒烯;纳米管;

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