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UV and corrosion protective behavior of polymer hybrid coating on mild steel

机译:温和钢上聚合物杂交涂层的UV和腐蚀保护性能

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Poly[(pyridine-4-yl-methyl)methacrylate-co-butyl methacrylate] [poly(PyMMA-co-BMA)] and its ZnO nanocomposites [poly(PyMMA-co-BMA)/ZnO] were coated on the mild steel substrate (MS) to improve the corrosion resistance by blocking the destructive ultraviolet radiation (UV-radiation) and corrosive ions as well. The optical and anticorrosive properties of poly(PyMMA-co-BMA) and poly(PyMMA-co-BMA)/ZnO (1.0, 1.5, and 2.5 wt %) coatings were evaluated. The surface characterization techniques like UV visible spectroscopy and scanning electron microscope were taken to confirm the formation of poly(PyMMA-co-BMA) and poly(PyMMA-co-BMA)/ZnO (2.5 wt %) coating on MS. The optical studies revealed that the poly(PyMMA-co-BMA)/ZnO (2.5 wt %) coating displays excellent UV blocking properties than other nanocomposite coatings (1.0 and 1.5 wt %). The potentiodynamic polarization and electrochemical impedance spectroscopy studies show that the poly(PyMMA-co-BMA) and poly(PyMMA-co-BMA)/ZnO (1.0, 1.5, and 2.5 wt %) coated MS in 3.5% (w/v) NaCl provides better protection against corrosion. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46175.
机译:聚[(吡啶-4-基 - 甲基)甲基丙烯酸叔丁酯] [聚(Pymma-Co-BMA)]及其ZnO纳米复合材料[聚(Pymma-Co-BMA)/ ZnO]涂覆在低碳钢上基板(MS)通过阻断破坏性紫外线(UV-辐射)和腐蚀性离子来改善耐腐蚀性。评价聚(Pymma-Co-BMA)和聚(Pymma-Co-BMA)/ ZnO(1.0,1.5和2.5wt%)涂层的光学和防腐蚀性能。采用UV可见光谱和扫描电子显微镜等表面表征技术,以确认MS上的聚(Pymma-Co-BMA)和聚(Pymma-Co-BMA)/ ZnO(2.5wt%)涂层的形成。光学研究表明,聚(Pymma-Co-BMA)/ ZnO(2.5wt%)涂层显示出优于其他纳米复合涂层(1.0和1.5wt%)的优异的UV阻断性能。电位动力学偏振和电化学阻抗光谱研究表明,聚(Pymma-Co-BMA)和聚(Pymma-Co-BMA)/ ZnO(1.0,1.5和2.5wt%)涂覆MS,3.5%(w / v) NACL提供更好的防腐蚀保护。 (c)2017 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2018,135,46175。

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