首页> 外文期刊>Journal of Applied Polymer Science >Influence of processing conditions on mechanical properties of blends of styrenic block copolymer and poly(phenylene oxide): Miscibility and microdomain size
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Influence of processing conditions on mechanical properties of blends of styrenic block copolymer and poly(phenylene oxide): Miscibility and microdomain size

机译:加工条件对苯乙烯嵌段共聚物混合物机械性能的影响:混溶性和微达米尺寸

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摘要

The effect of processing conditions on mechanical properties of poly(styrene-b-ethylene-co-butylene-b-styrene) (SEBS) and poly(2,6-dimethy-1,4-phenylene oxide) (PPO) blends were investigated. Differential scanning calorimetry and small angle X-ray scattering were used to study the miscibility and d-spacing of the blends. The processing temperature plays an important role in mechanical properties. PPO works as filler and weakens mechanical properties when the processing temperature is below 230 degrees C. As the processing temperature exceeds 230 degrees C, PPO incorporates into the PS blocks of SEBS and the performance enhances with increasing temperature due to a better miscibility. The strong shear stress is beneficial to the dispersion of PPO into SEBS matrix and more PPO incorporates into PS blocks during melt processing, resulting in the better mechanical properties and a larger d-spacing. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46123.
机译:研究了加工条件对聚(苯乙烯-B-乙烯 - 丁烯-B-苯乙烯)(SEBB)和聚(2,6-二甲基-1,4-氧化烯)(PPO)共混物的机械性能的影响 。 差分扫描量热法和小角度X射线散射用于研究混合物的混溶性和D-间距。 加工温度在机械性能中起重要作用。 当加工温度低于230℃时,PPO作为填充物削弱和削弱机械性能。随着加工温度超过230℃,PPO包含到SEBS的PS块中,并且由于更好的溶解性而增加温度随着温度的增加而增强。 强剪切应力有利于PPO将PPO分散到SEBS基质中,并且在熔融加工过程中,更多PPO掺入PS嵌段中,导致机械性能更好和更大的D-间距。 (c)2017 Wiley期刊,Inc.J.Phill。 聚合物。 SCI。 2018,135,46123。

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