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The effect of sodium stearate-modified hydrocalumite on the thermal stability of poly(vinyl chloride)

机译:硬脂酸钠改性碳氢化合物对聚(氯乙烯)热稳定性的影响

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Hydrocalumite as a new-type of thermal stabilizer used in poly(vinyl chloride) resin had been well prepared by using precipitation transformation method. The as-prepared hydrocalumite was then modified by sodium stearate in different condition including temperature, stirring time, and the amount of sodium stearate. Scanning electron microscopy tests demonstrate that hydrocalumite had been well modified. Illustrated by activation grade, the static oven heat aging experiments and the rate of thermal weight loss, it turns out that the best modification condition is when the addition of sodium stearate is 6% of hydrocalumite (wt), the reacting temperature is 90 degrees C, and the stirring time is 100 min. Static thermal aging test shows that the aging time got improved at least 30 min under the high temperature of 190 degrees C, and the time when Congo red test paper began to turn blue for modified hydrocalumite is 20 min longer than that of unmodified hydrocalumite. All results turn out to be that the hydrocalumite modified by sodium stearate in such condition had good compatibility with poly(vinyl chloride) and presented better thermal stability. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 45758.
机译:通过使用沉淀转化方法,通过使用沉淀转化方法充分地制备了氢化物作为聚(氯乙烯)树脂中使用的新型热稳定剂。然后在不同条件下通过硬脂酸钠改性AS制备的氢氧化物,包括温度,搅拌时间和硬脂酸钠的量。扫描电子显微镜测试表明,含氢过热化已变得很好。通过活化等级,静态烘箱热老化实验和热量损失的速率说明,事实证明,最佳改性条件是当加入硬脂酸钠是氢化油石(WT)的6%时,反应温度为90℃ ,搅拌时间为100分钟。静态热老化试验表明,在190℃的高温下老化时间在高温下改善了至少30分钟,刚果红色试纸开始变为改性烃的蓝色的时间比未改性的含氢氢化物的长度为20分钟。所有结果都结果在于这种条件下硬脂酸钠改性的氢化石油与聚(氯乙烯)具有良好的相容性,并呈现出更好的热稳定性。 (c)2017 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2018,135,45758。

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