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Synthesis and evaluation of interaction parameters of synthetic elastin‐derived polypentapeptide with poly(vinylpyrrolidone) in solution and solid phase

机译:用聚(乙烯基吡咯烷酮)在溶液和固相中合成弹性蛋白衍生多肽相互作用参数的合成与评价

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ABSTRACT > The parent repeating sequence of elastin, poly(GVGVP) has been synthesized by solution phase method and characterized by 13C and 1 H‐NMR spectroscopy. The poly(GVGVP) and poly(vinyl pyrrolidone) (PVP) interactions have been examined in solution phase by the viscometric method at 24?°C. The interaction parameters such as α, β, μ, and Δ[η] <sub> m </sub> indicated the miscible nature of poly(GVGVP)/PVP blends. Immiscibility occurred when the quantity of poly(GVGVP) is lesser than 60%. In the solid phase, Fourier transform infrared spectroscopic scrutiny of the thin films of poly(GVGVP)/PVP blends indicated the presence of strong intermolecular interaction such as hydrogen bonds linking the blend components. This result was further supported by glass transition temperature ( T <sub> g </sub> ), scanning electron microscopic, and X‐ray diffraction studies. The blending of poly(GVGVP) with PVP may provide an opportunity to produce new materials for potential biomedical applications. ? 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46699. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”> <title type =“main”>抽象</ title> >弹性蛋白,poly的父重复序列( GVGV通过溶液相法合成,其特征在于13C和<SUP> 1 </ SOP> H-NMR光谱。在24℃下,通过粘度法在溶液相中检查了聚(GVGV)和聚(乙烯基吡咯烷酮)(PVP)相互作用。相互作用参数,如α,β,μ和Δ[η] <sub> m </ su>表示poly(gvgvp)/ pvp混合物的混溶性。当聚(GVGV)的数量小于60%时,发生不混溶。在固相中,聚(GVGVP)/ PVP共混物的傅里叶变换红外光谱仔细筛选表明存在强的分子间相互作用,例如连接共混组分的氢键。通过玻璃化转变温度( T </ i> <sub> <碘>),扫描电子显微镜和X射线衍射研究进一步支持该结果。 Poly(GVGVP)与PVP的混合可以为潜在的生物医学应用产生新材料的机会。还是2018 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2018 </ b>, 135 </ i>,46699. </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-33581/'>《Journal of Applied Polymer Science》</a> <b style="margin: 0 2px;">|</b><span>2018年第40期</span><b style="margin: 0 2px;">|</b><span>共14页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mahesh B.&option=202" target="_blank" rel="nofollow">Mahesh B.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nanjundaswamy G. S.&option=202" target="_blank" rel="nofollow">Nanjundaswamy G. S.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gowda D. Channe&option=202" target="_blank" rel="nofollow">Gowda D. Channe;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Siddaramaiah&option=202" target="_blank" rel="nofollow">Siddaramaiah;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryJSS Academy of Technical EducationBangalore 560?060 India;</p> <p>Department of ChemistryJSS Academy of Technical EducationBangalore 560?060 India;</p> <p>Department of Studies in Chemistry ManasagangotriUniversity of MysoreMysore 570?006 India;</p> <p>Department of Polymer Science and TechnologySri Jayachamarajendra College of EngineeringMysore 570?006 India;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1821.html" title="高分子化合物工业(高聚物工业)">高分子化合物工业(高聚物工业);</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=biomaterials&option=203" rel="nofollow">biomaterials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=blends&option=203" rel="nofollow">blends;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrogen bonding&option=203" rel="nofollow">hydrogen bonding;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=intermolecular interactions&option=203" rel="nofollow">intermolecular interactions;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=miscibility studies&option=203" rel="nofollow">miscibility studies;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=proteins&option=203" rel="nofollow">proteins;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=poly(GVGVP)&option=203" rel="nofollow">poly(GVGVP);</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=PVP&option=203" rel="nofollow">PVP;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=spectroscopy&option=203" rel="nofollow">spectroscopy;</a> </p> <div class="translation"> 机译:生物材料;融合;氢键;分子间相互作用;混溶性研究;蛋白质;聚(GVGVP);PVP;光谱; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020590040.html">Synthesis and evaluation of interaction parameters of synthetic elastin‐derived polypentapeptide with poly(vinylpyrrolidone) in solution and solid phase</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mahesh B.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mahesh B.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nanjundaswamy G. 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