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Properties of poly(butylene adipate-co-terephthalate) and sunflower head residue biocomposites

机译:聚(丁烯己二酸丁二醇酯)和向日葵渣生物复合材料的性质

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摘要

Utilization of low-value agricultural waste for polymer composite materials has great environmental and economical benefits. Sunflower head residue (SHR) as an agricultural waste may be used as a reinforcement in polymeric materials because of its fiber characteristics. In this work, composites of biodegradable poly(butylene adipate-co-terephthalate) (PBAT) and SHR were prepared via melt-extrusion compounding. To improve interfacial compatibility, maleic anhydride (MA) grafted PBAT (PBAT-g-MA) was prepared and used as a compatibilizer for the PBAT/SHR composites. The effects of the concentrations of SHR and PBAT-g-MA on the morphology, mechanical properties, melt rheology, and water resistance of the composites were examined. Interfacial adhesion between phases in the PBAT/SHR composites was enhanced by the introduction PBAT-g-MA as interface-strengthening agent, resulting in improved mechanical properties and moisture resistance of the composite. (C) 2016 Wiley Periodicals, Inc.
机译:利用低价农业废物的聚合物复合材料具有很大的环境和经济效益。 由于其纤维特性,葵花籽头残留物(SHR)作为农业废物可用作聚合物材料中的增强物。 在这项工作中,通过熔融挤出复合制备可生物降解的聚(丁二酸酯 - 共 - 对苯二甲酸丁二醇酯)(PBAT)和SHR的复合材料。 为了改善界面相容性,制备马来酸酐(MA)接枝PBAT(PBAT-G-MA)并用作PBAT / SHC复合材料的增容剂。 检查了SHR和PBAT-G-MA浓度对复合材料的形态,机械性能,熔体流变学和耐水性的影响。 通过引入PBAT-G-MA作为界面强化剂,增强了PBAT / SHC复合材料中相之间的界面粘附,导致复合材料的机械性能和防潮性改善。 (c)2016 Wiley期刊,Inc。

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