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Effects of ultrasonic vibration on the rheological behavior of high-density polyethylene composites filled with flash aluminum flake pigments

机译:超声振动对闪光铝薄片颜料填充高密度聚乙烯复合材料的流变行为的影响

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摘要

The metallic effect of polymer composites was produced through the loading of flash aluminum flake pigments (FAFPs) into polymers. This production method could eliminate postprocessing techniques, such as spray coating, painting, or metallization. We used a self-improved, ultrasound-assisted capillary rheometer to explore the rheological behavior of high-density polyethylene composites filled with FAFPs in the absence and presence of ultrasound treatment. The effects of the ultrasound intensity, experimental temperature, filler content, and particle size on the composite viscosity were studied. The results show that the composite viscosity not only decreased as the ultrasound intensity, experimental temperature, and particle size increased but also decreased as the filler content decreased. A viscosity model of the polymer melts was proposed to illustrate the relationship between the viscosity and ultrasonic intensity. The viscosity obeyed the equations under ultrasonic vibration. The predicted results for the composite viscosity complied greatly with the experimental values. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44906.
机译:通过将闪光铝剥落颜料(FAFP)加载到聚合物中产生聚合物复合材料的金属效果。该生产方法可以消除后处理技术,例如喷涂,涂漆或金属化。我们使用了自我改善的超声辅助毛细管流变仪,探讨了在没有和存在超声处理的情况下填充有FAFP的高密度聚乙烯复合材料的流变行为。研究了超声强度,实验温度,填料含量和粒度对复合粘度的影响。结果表明,随着填料含量降低,复合粘度不仅随着超声强度,实验温度和粒度而降低而且降低。提出了聚合物熔体的粘度模型,以说明粘度和超声波强度之间的关系。粘度在超声波振动下遵循了方程。对复合粘度的预测结果大大符合实验值。 (c)2017 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2017,134,44906。

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