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Core-shell structure of carbon nanotube nanocapsules reinforced poly(lactic acid) composites

机译:碳纳米管纳米腐植物增强聚(乳酸)复合材料的核 - 壳结构

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In this study core-shell structure of carbon nanotube (CNT) nanocapsules, which aimed at toughening poly(lactic acid) (PLA) were designed by a synthetic strategy consisting of two reaction steps. The first step was to produce reactive chemical bond to bridge CNTs and PLA. So coupling agent KH570 was used to modify CNTs (CNTs-KH570). The second step involved ring open polymerization of lactide (LA). Lactide polymerized into PLA under catalysis and meanwhile grafted onto CNTs via KH570 (CNTs-KH570-PLA). Thus, the CNTs nanocapsules were constructed. Fourier transform infrared spectroscopy (FTIR) showed coupling agent KH570 succeeded in linking CNTs and PLA during LA polymerization. In addition, scanning electron microscopy (SEM) and transmission electron microscope (TEM) indicated CNTs dispersed homogeneous in PLA matrix and the compatibility between them was excellent. The mechanical test also suggested the designed nanocapsules had good effect on toughening PLA composites. This research found one economical and simple way to improve PLA mechanical properties and further broaden its application in many fields. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44919.
机译:在该研究中,通过由两个反应步骤组成的合成策略,设计了碳纳米管(CNT)纳米腐植物的碳纳米管(CNT)纳米腐植体的核心 - 壳结构由两个反应步骤组成的合成策略设计。第一步是产生反应性化学键以桥接CNT和PLA。因此,偶联剂KH570用于改性CNT(CNT-KH570)。第二步涉及丙交酯(LA)的环开放聚合。将丙交酯聚合到催化作用下PLA,同时通过KH570(CNT-KH570-PLA)接枝到CNT上。因此,构建了CNT纳米胶囊。傅里叶变换红外光谱(FTIR)显示偶联剂KH570成功在LA聚合期间将CNT和PLA连接。另外,扫描电子显微镜(SEM)和透射电子显微镜(TEM)指示在PLA矩阵中分散的CNT,它们之间的相容性优异。机械测试还提出了设计的纳米胶囊对增韧PLA复合材料具有良好的影响。该研究发现了一种经济和简单的方法来改善PLA机械性能,并进一步扩大其在许多领域的应用。 (c)2017 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2017,134,44919。

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