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Lasting high surface energy co-polyester ionomer and its application in laminated tin-free steel

机译:持续高表面能共聚聚酯离聚物及其在层压铁钢中的应用

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A lasting high surface energy co-polyester poly[ethylene terephthalate-co-ethylene isophthalate sodiosulfonate-co-poly(ethylene glycol)] polyester (PEPST) was synthesized and applied in laminated tin-free steel (TFS). The structures and properties of the copolyester were characterized by nuclear magnetic spectra (1(H)-NMR), thermogravimetry, differential scanning calorimetry, polarized optical microscopy, and surface energy tests. Meanwhile, the peel strength and corrosion resistance of the co-polyester film were also measured. The results confirm that an improvement in the lamination temperature leads to PEPST film peel strength increases, and crystalline and corrosion resistance decrease. Based on the purpose of reducing a detrimental effect on corrosion resistance, a reasonable lamination temperature was determined. Scanning electron microscope and energy dispersive X-ray analysis prove the interface combination morphology of laminated TFS. Anticorrosion property analysis shows PEPST film has good anticorrosion performance. (C) 2017 Wiley Periodicals, Inc.
机译:合成了持久的高表面能共聚聚酯聚α,合成亚乙二醇酯 - 共聚乙烯酸酯 - 共聚(乙二醇)聚酯(铅酸),并施加在层压锡钢(TFS)中。通过核磁光谱(1(H)-NMR),热重率,差示扫描量热法,偏振光显微镜和表面能测试,表征共聚酯的结构和性质。同时,还测量了共聚酯薄膜的剥离强度和耐腐蚀性。结果证实,层压温度的改善导致薄膜剥离强度的增加,并且结晶和耐腐蚀性降低。基于降低对耐腐蚀性的不利影响的目的,测定合理的层压温度。扫描电子显微镜和能量分散X射线分析证明了层压TFS的界面组合形态。防腐性质分析显示佩佩薄膜具有良好的防腐性能。 (c)2017 Wiley期刊,Inc。

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