Magnetism and optical properties of Yb3Al5O12 hosted Er3+ - experiment and theory

Sedmidubsky David; Jakes Vit; Rubesova Katerina; Nekvindova Pavla; Hlasek Tomas; Yatskiv Roman; Novak Pavel

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Magnetism and optical properties of Yb3Al5O12 hosted Er3+ - experiment and theory

机译：YB3AL5O12托管ER3 + - 实验与理论的磁性和光学性质

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Using the recently developed method based on a combination of DFT plane wave code applied to extract the crystal field parameters and a local atomic like Hamiltonian involving electron-electron, spin-orbit and Zeeman terms we calculated the energy levels of ground and excited multiplets of Yb3+ and Er3+ ions hosted in ytterbium and yttrium aluminum garnet (YbAG and YAG) including their crystal and magnetic field splitting. The obtained energy levels and derived magnetic properties are compared with the experimental data from magnetometry, photoluminiscence and near-infrared spectroscopy. (C) 2019 Elsevier B.V. All rights reserved.

机译：利用最近的开发方法基于应用于提取晶体场参数的DFT平面波代码的组合，以及涉及电子 - 电子的哈密顿人类的局部原子，旋转轨道和塞曼术语，我们计算了YB3 +的地面和激励多重的能量水平。在镱和钇铝石榴石（YBAG和YAG）中载有ER3 +离子，包括它们的晶体和磁场分裂。将获得的能量水平和衍生的磁性与来自磁体，光荧光和近红外光谱的实验数据进行比较。（c）2019 Elsevier B.v.保留所有权利。

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来源
《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |2019年第2019期|共6页
作者
Sedmidubsky David; Jakes Vit; Rubesova Katerina; Nekvindova Pavla; Hlasek Tomas; Yatskiv Roman; Novak Pavel;
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作者单位

Univ Chem &

Technol Dept Inorgan Chem Tech 5 Prague 16628 6 Czech Republic;

Univ Chem &

Technol Dept Inorgan Chem Tech 5 Prague 16628 6 Czech Republic;

Univ Chem &

Technol Dept Inorgan Chem Tech 5 Prague 16628 6 Czech Republic;

Univ Chem &

Technol Dept Inorgan Chem Tech 5 Prague 16628 6 Czech Republic;

Univ Chem &

Technol Dept Inorgan Chem Tech 5 Prague 16628 6 Czech Republic;

Czech Acad Sci Inst Photon &

Elect Chaberska 57 Prague 18251 8 Czech Republic;

Czech Acad Sci Inst Phys Cukrovarnicka 10 Prague 16200 6 Czech Republic;

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原文格式 PDF
正文语种 eng
中图分类合金学与各种性质合金;金属材料;
关键词
Ytterbium-aluminium garnet; Erbium doping; Crystal field parameters; Luminiscence; Magnetism;

机译：镱 - 铝石榴石;铒掺杂;水晶场参数;发光;磁性;

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Magnetism and optical properties of Yb3Al5O12 hosted Er3+ - experiment and theory

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