首页> 外文期刊>Journal of Chemical and Engineering Data: the ACS Journal for Data >Vapor-Liquid Equilibrium for Binary Mixtures of 3-Cyano-1-butene + RS-4-Vinyl-1-cyclohexene, 3-Cyano-1-butene + ZE-1-Cyano-2-butene and RS-4-Vinyl-1-cyclohexene plus ZE-1-Cyano-2-butene
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Vapor-Liquid Equilibrium for Binary Mixtures of 3-Cyano-1-butene + RS-4-Vinyl-1-cyclohexene, 3-Cyano-1-butene + ZE-1-Cyano-2-butene and RS-4-Vinyl-1-cyclohexene plus ZE-1-Cyano-2-butene

机译:二元混合物的蒸汽液平衡为3-氰基-1-丁烯+ RS-4-乙烯基-1-环己烯,3-氰基-1-丁烯+ ZE-1-氰基-2-丁烯和RS-4-乙烯基 - 1-环己烯加ZE-1-氰基-2-丁烯

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摘要

The isobaric (vapor + liquid) equilibrium (VLE) at 100.0 kPa data of two binary mixtures (3-cyano-1-butene + RS-4-vinyl-1-cyclohexene) and (3-cyano-1-butene + ZE-1-cyano-2-butene), and the isothermal (vapor + liquid) equilibrium at (373.15, 383.15 and 403.15) K data of (RS-4-vinyl-1-cyclohexene + ZE-1-cyano-2-butene) have been determined. These VLE data were checked with both point-to-point test and direct test, and they proved to be thermodynamically consistent. Further the (vapor + liquid) equilibrium data were correlated by two local composition models (Wilson + NRTL), and the interaction energy parameters of the models were optimized by least-squares. All calculated and experimental values show a very good agreement and consistency.
机译:在两个二元混合物(3-氰基-1-丁烯+ RS-4-乙烯基-1-环己烯)的100.0kPa数据中的等异(蒸汽+液体)平衡(VLE)和(3-氰基-1-丁烯+ ZE- 1-氰基-2-丁烯)和等温(蒸汽+液体)平衡(373.15,383.15和403.15)K数据(RS-4-乙烯基-1-环己烯+ ZE-1-氰基-2-丁烯) 已经确定了。 使用点对点测试和直接测试检查这些VLE数据,并证明它们是热力学上的一致性。 此外,通过两个局部组成模型(Wilson + NRTL)相关(蒸汽+液体)平衡数据,并且通过最小二乘来优化模型的相互作用能量参数。 所有计算和实验值都显示出非常良好的一致性和一致性。

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    Hubei Univ Nationalities Coll Biol Sci &

    Technol Hubei Key Lab Biol Resources Protect &

    Utilizat Enshi 445000 Peoples R China;

    Hubei Univ Nationalities Coll Biol Sci &

    Technol Hubei Key Lab Biol Resources Protect &

    Utilizat Enshi 445000 Peoples R China;

    Sichuan Univ Dept Pharmaceut &

    Biol Engn Coll Chem Engn Chengdu 610065 Sichuan Peoples R China;

    Sichuan Univ Dept Pharmaceut &

    Biol Engn Coll Chem Engn Chengdu 610065 Sichuan Peoples R China;

    Hubei Univ Nationalities Coll Biol Sci &

    Technol Hubei Key Lab Biol Resources Protect &

    Utilizat Enshi 445000 Peoples R China;

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  • 正文语种 eng
  • 中图分类 化学工业;
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