Evaluation of temperature and pressure effects on retention in supercritical fluid chromatography on polar stationary phases

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Evaluation of temperature and pressure effects on retention in supercritical fluid chromatography on polar stationary phases

机译：对极性静止相超临界流体色谱法潴留的温度和压力影响的评价

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Four polar stationary phases (ethylene-bridged hybrid silica, cyanopropyl, 2-ethylpyridine, and zwitterionic sulfobetaine) have been characterized in supercritical fluid chromatography (SFC) by linear free energy relationships (LFER) method with an extended set of Abraham's descriptors. Temperature (25-55 degrees C) and pressure (110-180 bar) effects on analyte retention, separation selectivity and LFER-coefficients of chromatographic systems have been studied using the 89 test compounds of various chemical classes and carbon dioxide - methanol (9:1 v/v) binary solvent as a mobile phase.

机译：通过线性自由能量关系（LEFE）方法具有延长的亚伯拉罕的描述符，在超临界流体色谱（SFC）中表征了四个极静止相（乙烯 - 桥接杂交二氧化硅，氰基丙基，2-乙基吡啶和两性离子磺基）。温度（25-55摄氏度）和压力（110-180巴）对分析物保留的影响，使用各种化学类别和二氧化碳 - 甲醇的89次试验化合物研究了色谱系统的分离选择性和杠杆系数（9： 1 v / v）二元溶剂作为流动阶段。

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《Journal of chromatography, A: Including electrophoresis and other separation methods》 |2020年第2020期|共10页
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正文语种 eng
中图分类分析化学;
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Supercritical fluid chromatography; Stationary phase; Temperature; Pressure; Linear free energy relationships;

机译：超临界流体色谱;固定相;温度;压力;线性自由能关系;

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1. Evaluation of temperature and pressure effects on retention in supercritical fluid chromatography on polar stationary phases [J] . Journal of chromatography, A: Including electrophoresis and other separation methods . 2020,第期

机译：对极性静止相超临界流体色谱法潴留的温度和压力影响的评价
2. TEMPERATURE AND PRESSURE EFFECTS ON SOLUBILITY IN SUPERCRITICAL CARBON DIOXIDE AND RETENTION IN SUPERCRITICAL FLUID CHROMATOGRAPHY [J] . Lou XW, Janssen HG, Cramers CA Journal of chromatography, A: Including electrophoresis and other separation methods . 1997,第1a2期

机译：温度和压力对超临界二氧化碳溶解度的影响以及超临界流体色谱中的保留
3. Efficient preparative separation of 6-(4-aminophenyl)-5-methyl-4, 5-dihydro-3(2H)-pyridazinone enantiomers on polysaccharide-based stationary phases in polar organic solvent chromatography and supercritical fluid chromatography [J] . Cheng Lingping, Cai Jianfeng, Fu Qing, Journal of separation science. . 2019,第15期

机译：高效的制备分离6-（4-氨基苯基）-5-甲基-4,5-二氢-3（2H） - 在极性有机溶剂色谱和超临界流体色谱中基于多糖的静止相的吡啶啉酮对映异构体
4. Relationship between retention for homologues and density of mobile phase in supercritical fluid chromatography [C] . Baozeng REN Beijing conference and exhibition on instrumental analysis;BCEIA . 2001

机译：超临界流体色谱中同系物保留率与流动相密度之间的关系
5. Synthesis of novel polar and chiral polysiloxane stationary phases for gas and supercritical fluid chromatography. [D] . Johnson, Deborah Finch. 1991

机译：用于气相和超临界流体色谱的新型极性和手性聚硅氧烷固定相的合成。
6. Comparison of Retention Behavior between Supercritical Fluid Chromatography and Normal-Phase High-Performance Liquid Chromatography with Various Stationary Phases [O] . Tsunehisa Hirose, Daniel Keck, Yoshihiro Izumi, 2019

机译：具有不同固定相的超临界流体色谱和正相高效液相色谱的保留行为比较
7. Effects of high concentrations of mobile phase additives on retention and separation mechanisms on a teicoplanin aglycone stationary phase in supercritical fluid chromatography [O] . Adrien Raimbault, Caroline West 2019

机译：高浓度的流动相添加剂对超临界流体色谱法临时糖苷固定相的保留和分离机制的影响
8. Supercritical Fluid Chromatography: The Effect of the Partial Molar Volume in the Stationary Phase on Retention [R] . Yonker, C. R. , Smith, R. D. 1988

机译：超临界流体色谱：固定相中部分摩尔体积对保留的影响

Evaluation of temperature and pressure effects on retention in supercritical fluid chromatography on polar stationary phases

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