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首页> 外文期刊>Journal of Materials Chemistry, A. Materials for energy and sustainability >Ultrahigh photothermal temperature in a graphene/conducting polymer system enables contact thermochemical reaction
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Ultrahigh photothermal temperature in a graphene/conducting polymer system enables contact thermochemical reaction

机译:石墨烯/导电聚合物体系中的超高光热温使得能够接触热化学反应

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摘要

Photothermal conversion in the near-infrared (NIR) wavelengths, wherein light energy is converted into heat energy, has attracted great interest and developed rapidly in recent years for its wide applications in health care, flexible electronics, energy and environmental fields. However, the photothermal temperature, as one of the most important parameters in the NIR photothermal conversion, still has not been effectively studied. Herein, we successfully achieved ultrahigh photothermal temperatures in a graphene/conducting polymer system. The surface temperature of the prepared free-standing reduced graphene oxide/polypyrrole (rGO/PPy) foam can be as high as 380 degrees C with 808 nm NIR irradiation at 2.6 W cm(-2), and the surface temperature of the rGO/PPy film on the polydimethylsiloxane (PDMS) substrate can be as high as 310 degrees C under the same conditions. The photothermal energy has been used for burning, thermopolymerization, alloying reactions and thermal decomposition reactions, providing new directions for photothermal conversion beyond photothermal therapy and energy utilization.
机译:在近红外(NIR)波长中的光热转换,其中光能被转化为热能,吸引了极大的兴趣,并且近年来迅速开发,因为其在保健,柔性电子,能量和环境领域的广泛应用。然而,作为NIR光热转化中最重要的参数之一的光热温度仍未有效地研究。在此,我们在石墨烯/导电聚合物体系中成功地实现了超高的光热温度。制备的独立式的石墨烯氧化物/聚吡咯(RGO / PPY)泡沫的表面温度可以高达380℃,具有808nm的NIR照射,在2.6W cm(-2),以及RGO的表面温度/在聚二甲基硅氧烷(PDMS)基底上的PPY膜在相同条件下可以高达310℃。光热能量已被用于燃烧,热聚合,合金化反应和热分解反应,为光热转化率的新方向提供超热疗法和能量利用。

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