Synthesis, single crystal X-ray structure and vibrational spectroscopic characterization study of a new hybrid material crystal: Bis(2,4,6-trihydroxy-1,3,5-triazin-1-ium) bischloride monohydrate

AitYoucef Hakima Chenefa; Bourzami Riadh

首页> 外文期刊>Journal of Molecular Structure >Synthesis, single crystal X-ray structure and vibrational spectroscopic characterization study of a new hybrid material crystal: Bis(2,4,6-trihydroxy-1,3,5-triazin-1-ium) bischloride monohydrate

【24h】

Synthesis, single crystal X-ray structure and vibrational spectroscopic characterization study of a new hybrid material crystal: Bis(2,4,6-trihydroxy-1,3,5-triazin-1-ium) bischloride monohydrate

机译：新型杂交材料晶体的合成，单晶X射线结构和振动光谱表征研究：BIS（2,4,6-三羟基-1,3,5-三嗪-1-Ium）双氯化物一水合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new hybrid material bis(2,4,6-trihydroxy-1,3,5-triazin-1-ium) bischloride monohydrate (2C(3)H(4)N(3)O(3)(+)center dot 2Cl(-)center dot H2O) as a crystal has been synthesized and its structure was identified by single-crystal X-ray diffraction and studied by UV-Vis, FT-IR, FT-Raman and H-1 NMR. The crystal of 2C(3)H(4)N(3)O(3)(+)center dot 2Cl(-)center dot H2O belongs to monoclinic with C-2/m space group system with Z = 4, a = 12.3845 (9) angstrom, b = 17.6236 (14) angstrom, c = 7.0260 (5) angstrom and beta = 115.341 (2)degrees. The UV-Vis spectrum shows that the compound is transparent in visible and UV near visible domains. The FT-IR, FT-RAMAN and H-1 NMR spectra of the crystal were discussed on the basis of crystallographic structure and the results were coherent and provides spectroscopic evidence for the crystal formation. In addition, the thermal decomposition of 2C(3)H(4)N(3)O(3)(+)center dot 2Cl(-)center dot H2O has been also studied by TGA/DTG and DSC techniques and reveals that the material has a good thermal stability with the melting point about 310 degrees C. (C) 2019 Published by Elsevier B.V.

机译：新的杂交材料BIS（2,4,6-三羟基-1,3,5-三嗪-1-1-Ium）双氯化物一水合物（2℃（3）H（4）N（3）O（3）（+）中心点已经合成了作为晶体的2Cl（ - ）中心点H2O），其结构通过单晶X射线衍射鉴定，并通过UV-Vis，FT-IR，Ft-Raman和H-1 NMR研究。 2C（3）H（4）N（3）o（3）o（+）中心点2Cl（ - ）中心点H2O属于单斜替氏的Z = 4，a = 12.3845（9）Angstrom，B = 17.6236（14）埃，C = 7.0260（5）Angstrom和Beta = 115.341（2）度。 UV-Vis光谱表明该化合物在可见域附近的可见和UV中是透明的。基于晶体结构讨论晶体的FT-IR，Ft-拉曼和H-1 NMR光谱，结果是相干的，并为晶体形成提供光谱探测。此外，图2C的热分解（3）H（4）N（3）O（3）（+）中央点2CL（ - ）中心点H2O已经通过TGA / DTG和DSC技术也进行了研究并揭示了材料具有良好的热稳定性，熔点约为310摄氏度C.（c）2019年由Elsevier BV发布

著录项

来源
《Journal of Molecular Structure》 |2019年第2019期|共7页
作者
AitYoucef Hakima Chenefa; Bourzami Riadh;
展开▼
作者单位

Univ Ferhat Abbas Setif 1 Fac Technol Dept Enseignement Base Technol Setif Algeria;

Univ Setif Emerged Mat Unit Setif 19000 Algeria;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类分子结构;
关键词
Melamine; X-ray diffraction; FT-IR; FT-Raman; TGA; DSC;

机译：三聚氰胺;X射线衍射;FT-IR;FT-Raman;TGA;DSC;
入库时间 2022-08-19 19:44:53

相似文献

外文文献
中文文献
专利

1. Synthesis, single crystal X-ray structure and vibrational spectroscopic characterization study of a new hybrid material crystal: Bis(2,4,6-trihydroxy-1,3,5-triazin-1-ium) bischloride monohydrate [J] . AitYoucef Hakima Chenefa, Bourzami Riadh Journal of Molecular Structure . 2019,第期

机译：新型杂交材料晶体的合成，单晶X射线结构和振动光谱表征研究：BIS（2,4,6-三羟基-1,3,5-三嗪-1-Ium）双氯化物一水合物
2. Synthesis, spectroscopic characterization and X-ray single crystal structures of trans-bis[4-methoxyphenyl (3-methylbutyl) dithiophosphinato] nickel(II) and bis [4-methoxyphenyl (3-methylbutyl) dithiophosphinato]cobalt(II) complexes [J] . Ertugrul Gazi Saglam, Omer Celik, Hamza Yilmaz Transition Metal Chemistry . 2010,第4期

机译：反式双[4-甲氧基苯基（3-甲基丁基）二硫代膦酸酯]镍（II）和双[4-甲氧基苯基（3-甲基丁基）二硫代膦酸酯]钴（II）配合物的合成，光谱表征和X射线单晶结构
3. Synthesis, spectroscopic characterization and X-ray single crystal structures of trans-bis[4-methoxyphenyl (3-methylbutyl) dithiophosphinato] nickel(II) and bis [4-methoxyphenyl (3-methylbutyl) dithiophosphinato]cobalt(II) complexes [J] . Ertuğrul Gazi Sağlam, Ömer Çelik, Hamza Yılmaz, Transition Metal Chemistry . 2010,第4期

机译：反式双[4-甲氧基苯基（3-甲基丁基）二硫代膦酸酯]镍（II）和双[4-甲氧基苯基（3-甲基丁基）二硫代膦酸酯]钴（II）配合物的合成，光谱表征和X射线单晶结构
4. X-ray diffraction, spectroscopic and mechanical studies on potential organic NLO materials of metaNitroaniline and N-3-Nitrophenyl Acetamide single crystals [C] . S. Senthil, J. Madhavan International Conference on Materials Science and Technology . 2015

机译：X射线衍射，光谱和机械研究亚硝基胺和N-3-硝基苯基乙酰胺单晶的潜在有机NLO材料
5. High-pressure catalytic reactions of six-carbon hydrocarbons on platinum single-crystals and nanoparticles: A sum frequency generation vibrational spectroscopic and kinetic study [D] . Bratlie, Kaitlin 2007

机译：六碳碳氢化合物在铂单晶和纳米颗粒上的高压催化反应：总频率产生振动光谱和动力学研究
6. Formation of Prenylated Chalcone Xanthohumol Cocrystals: Single Crystal X-ray Diffraction Vibrational Spectroscopic Study Coupled with Multivariate Analysis [O] . Iwona Budziak, Marta Arczewska, Daniel M. Kamiński 2019

机译：异戊烯化查尔酮黄腐酚共晶体的形成：单晶X射线衍射振动光谱研究与多元分析
7. New Quasi-One-Dimensional Organic-Inorganic Hybrid Material: 1,3-Bis(4-piperidinium)propane Pentachlorobismuthate(III) Synthesis, Crystal Structure, and Spectroscopic Studies [O] . Hela Ferjani, Habib Boughzala 2014

机译：新的准一体式有机 - 无机杂化材料：1,3-双（4-哌啶）丙烷五氯生物铋（III）合成，晶体结构和光谱研究
8. Structure, Ordering, and Chemistry of Molecular Overlayers on Rh(111) and Rh(100) Single Crystal Surfaces: A Vibrational Spectroscopic and LEED (Low Energy Electron Diffraction) Crystallographic Study [R] . Kao, C. T. 1988

机译：Rh（111）和Rh（100）单晶表面上分子叠层的结构，排序和化学：振动光谱和LEED（低能电子衍射）晶体学研究

Synthesis, single crystal X-ray structure and vibrational spectroscopic characterization study of a new hybrid material crystal: Bis(2,4,6-trihydroxy-1,3,5-triazin-1-ium) bischloride monohydrate

摘要

著录项

相似文献

相关主题

期刊订阅