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Inclusion of alkyl alcohol guest molecules into a copper (II)-based hydrogen-bonded metal-organic framework

机译:将烷基醇客体分子包含成铜(II)的基于氢键金属 - 有机框架

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In this study, the investigation of a copper (II) complex, which is formed by a reaction between Cu2+ ions and pyridine-2,4-dicarboxylic acid, yielding the Cu(HPDCA)(2)(H2O)(2) compound. The previously mentioned copper (II) compound reacts with DL-alpha-methylbenzylamine, resulting in a complex yielding a bilayer framework containing a 5-coordinate copper (II) centre. The dissociated water molecule is assisting in the formation of a bilayer. This bilayer framework has the ability to include guest molecules, particularly alkyl alcohol molecules. The discussion of four guest included hydrogen-bonded frameworks are discussed in: (1) [alpha-methylbenzylammonium](2)Cu(PDCA)(2)(H2O), (2) [alpha-methylbenzylammonium](2)Cu(PDCA)(2)(H2O)center dot(1-octanol), (3) [alpha- methylbenzylammo nium](2)Cu( PDCA)(2)(H2O)center dot(2-octanol), (4) [alpha-methylbenzylammonium](2)Cu(PDCA)(2)(H2O)center dot(cyclohexanol). (C) 2019 Elsevier B.V. All rights reserved.
机译:在该研究中,通过Cu 2 +离子和吡啶-2,4-二羧酸之间的反应形成的铜(II)复合物的研究,得到Cu(HPDCA)(2)(2)(2)(2)化合物。 前面提到的铜(II)化合物与D1-α-甲基苄基胺反应,得到了含有5坐标铜(II)中心的双层框架的复合物。 离解水分子辅助形成双层。 这种双层框架具有能够包括客体分子,特别是烷基醇分子。 对四个客人的讨论包括氢键框架:(1)α-α-甲基苄基铵](2)Cu(PDCA)(2)(2)(2),(2)α(2)α(PDCA)(PDCA )(2)(H2O)中心点(1-辛醇),(3)αα(2)Cu(PDCA)(2)(H2O)中心点(2-辛醇),(4)α(4)[α - 甲基苄基铵](2)Cu(PDCA)(2)(H2O)中心点(环己醇)。 (c)2019 Elsevier B.v.保留所有权利。

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