首页> 外文期刊>Acta biomaterialia >Fluorine-substituted hydroxyapatite scaffolds hydrothermally grown from aragonitic cuttlefish bones.
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Fluorine-substituted hydroxyapatite scaffolds hydrothermally grown from aragonitic cuttlefish bones.

机译:氟取代的羟基磷灰石脚手架,由文石乌贼骨水热生长。

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摘要

Porous hydroxyapatite scaffolds with different levels of fluorine substitution (46% and 85%) on the OH sites were produced via hydrothermal transformation of aragonitic cuttlefish bones at 200 degrees C and calcination at temperatures up to 1200 degrees C. The increasing level of F substitution reduces the kinetics and probably the yield of the reaction. The incorporation of F in the lattice of hydroxypatite caused a lowering of the unit cell volume due to reduction of the length of the a-axis. The crystallites formed were close in size to bone-like apatite and were orientated along the a-axis rather than the c-axis. There was evidence of AB-type carbonated apatite.
机译:通过在200摄氏度下对文石乌贼骨进行水热转化并在高达1200摄氏度的温度下煅烧,可制得在OH位置具有不同水平的氟取代水平(46%和85%)的多孔羟基磷灰石支架。动力学和可能的反应产率。由于a轴长度的减少,在羟基磷灰石的晶格中掺入F导致晶胞体积的降低。形成的微晶尺寸接近于骨状磷灰石,并沿a轴而不是c轴取向。有AB型碳酸磷灰石的证据。

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