Sn-P-F containing glass matrix for the fabrication of phosphor-in-glass for use in high power LEDs

Yoo Heeyeon; Kouhara Yoshihiro; Yoon Hee Chang; Park Sang Jun; Oh Ji Hye; Do Young Rag

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Sn-P-F containing glass matrix for the fabrication of phosphor-in-glass for use in high power LEDs

机译：SN-P-F包含玻璃基质，用于制造玻璃玻璃，用于高功率LED

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In this study, we introduce a low-melting-point (MP) glass ceramic (GlaC) material which can be used to fabricate a phosphor-in-glass (PiG) with Y3Al5O12:Ce3+ (YAG) phosphor for the realization of high-power white-light-emitting diodes (WLEDs). PiG using a low-MP Sn-P-rich GlaC material, with simple fabrication at 230 degrees C, can address the drawbacks of the phosphor thermal degradation of currently developed PiGs with a high MP of more than 400 degrees C, and the yellowing of commercialized phosphor-insilicon binder (PiSB) materials. In addition, the low-MP PiG can serve as a heat sink due to its good thermal conductivity and good stability compared to those of commercialized PiSB materials. The optical properties of a low-MP PiG-based WLED are a luminous efficacy (LE) of 118 mu m W-1, an external quantum efficiency (EQE) of 0.33 and a color-rendering index (CRI) of 68 at 4275 K at an applied current of 350 mA. The simply fabricated and stable PiG-based WLED using the low-MP GlaC material will be a competitive candidate in the WLED lighting market.

机译：在这项研究中，我们引入了一种低熔点（MP）玻璃陶瓷（GLAC）材料，其可用于用Y3Al5O12：Ce3 +（YAG）磷光体来制造玻璃玻璃（猪），以实现高 - 电源白光发光二极管（WLED）。猪使用低MP Sn-P-P-P-P-P-PIM，在230℃下制造简单，可以解决当前开发的猪的荧光粉热降解的缺点，高于400℃的高MP，和泛黄商业化磷脂粘合剂（PISB）材料。此外，与商业化PISB材料相比，低MP猪可以用作散热器，与其良好的导热性和良好的稳定性相比。基于低MP猪的WLD的光学性质是118μmw-1的发光效率（Le），外部量子效率（EQE）为0.33，在4275k时为68的颜色呈现指数（CRI）在350 mA的施加电流下。使用Low-MP Glac材料简单地制造和稳定的猪WLOD将成为WLED照明市场的竞争候选者。

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来源
《RSC Advances》 |2016年第113期|共8页
作者
Yoo Heeyeon; Kouhara Yoshihiro; Yoon Hee Chang; Park Sang Jun; Oh Ji Hye; Do Young Rag;
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作者单位

Kookmin Univ Dept Chem Seoul 02707 South Korea;

YEJ GLASS Co Ltd Kagoshima Kagoshima 8990401 Japan;

Kookmin Univ Dept Chem Seoul 02707 South Korea;

YEK GLASS Co Ltd Seoul 06093 South Korea;

Kookmin Univ Dept Chem Seoul 02707 South Korea;

Kookmin Univ Dept Chem Seoul 02707 South Korea;

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正文语种 eng
中图分类化学;
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1. Sn-P-F containing glass matrix for the fabrication of phosphor-in-glass for use in high power LEDs [J] . Yoo Heeyeon, Kouhara Yoshihiro, Yoon Hee Chang, RSC Advances . 2016,第113期

机译：SN-P-F包含玻璃基质，用于制造玻璃玻璃，用于高功率LED
2. Sn–P–F containing glass matrix for the fabrication of phosphor-in-glass for use in high power LEDs [J] . Heeyeon Yoo, Yoshihiro Kouhara, Hee Chang Yoon, RSC Advances . 2016,第113期

机译：SN-P-F包含玻璃基质，用于制造玻璃玻璃，用于高功率LED
3. Low-Yellowing Phosphor-in-Glass for High-Power Chip-on-board White LEDs by Optimizing a Low-Melting Sn-P-F-O Glass Matrix [J] . Hee Chang Yoon, Kouhara Yoshihiro, Heeyeon Yoo, Scientific reports. . 2018,第1期

机译：通过优化低熔点SN-P-F-O玻璃基质，用于高功率芯片上白色LED的低黄色磷光体玻璃
4. High-power white LED packaging using phosphor-in-glass and its thermal reliability [C] . Yang Peng, Ruixin Li, Hao Cheng, China international forum on solid state lighting . 2016

机译：使用玻璃荧光粉的大功率白光LED封装及其热可靠性
5. Influence of material selection and fabrication process repeatability on mechanical properties of glass-polymer matrix composite structures [D] . Edwards, Charles 2011

机译：材料选择和制造工艺的可重复性对玻璃-聚合物基复合结构力学性能的影响
6. Low-Yellowing Phosphor-in-Glass for High-Power Chip-on-board White LEDs by Optimizing a Low-Melting Sn-P-F-O Glass Matrix [O] . Hee Chang Yoon, Kouhara Yoshihiro, Heeyeon Yoo, -1

机译：通过优化低熔点Sn-P-F-O玻璃基质实现高功率板载白光LED的黄变玻璃磷光体
7. Enhanced luminescence performance of CaO:Ce3+,Li+,F− phosphor and its phosphor-in-glass based high-power warm LED properties [O] . Jiankun Deng, Haoran Zhang, Xuejie Zhang, 2018

机译：CAO的增强发光性能：CE3 +，Li +，F-磷光体及其磷光体基大功率温暖LED性能
8. Fabrication and Materials Evaluation of High Performance Aligned Ceramic Fibre Reinforced Glass Matrix Composite [R] . Dawson, D. M., Preston, R. F., Purser, A. 1986

机译：高性能对准陶瓷纤维增强玻璃基复合材料的制备与材料评价

Sn-P-F containing glass matrix for the fabrication of phosphor-in-glass for use in high power LEDs

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