• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>RSC Advances >Effects of sulfur compounds on the hydrogenation and isomerization of 1-hexene over a sulfided CoMo catalyst for hydrodesulfurization
【24h】

Effects of sulfur compounds on the hydrogenation and isomerization of 1-hexene over a sulfided CoMo catalyst for hydrodesulfurization

机译：硫化合物对加氢硫化Como催化剂中1-己烯氢化和异构化的影响

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The transformation of olefins is crucial to the hydrodesulfurization (HDS) of fluid catalytic cracking (FCC) gasoline. The reactivity of 1-hexene was studied over a sulfided CoMo/Al2O3 catalyst. Effects of hydrogen sulfide (H2S) and three organic sulfur compounds on 1-hexene transformation were also investigated. As for the hydroconversion of 1-hexene, the double-bond isomerization (ISOM) of 1-hexene proceeded readily at lower temperatures while the hydrogenation (HYD) of 1-hexene and its isomers predominated at higher temperatures. The inhibiting effect of H2S on both isomerization and hydrogenation reactions resulted in the decline in 1-hexene HYD conversion. The saturation rate of 1-hexene increased sharply when H2S content decreased to below 100 mu g g(-1) S. It was also found that thiophene (T), 2-methylthiophene (2MT) and 3-methylthiophene (3MT) strongly inhibited the hydrogenation of 1-hexene. Furthermore, the inhibiting effect on 1-hexene HYD reaction originated from H2S generated by organic sulfide desulfurization. More isomerization products were obtained in the presence of sulfur compounds, probably attributable to the inhibition of sulfur compounds on the hydrogenation of 1-hexene and its isomers.
机译：烯烃的转化对于流体催化裂化（FCC）汽油的加氢脱硫（HDS）是至关重要的。在硫化ComO / Al 2 O 3催化剂上研究了1-己烯的反应性。还研究了硫化氢（H2S）和三种有机硫化合物对1-己烯转化的影响。至于1-己烯的水电转化，1-己烯的双键异构化（ISOM）在较低温度下易于进行，而1-己烯的氢化（HYD）及其异构体以较高的温度为主。 H2S对异构化和氢化反应的抑制作用导致1-己烯的转化率下降。当H 2 S含量降低至100μg（-1）S时，1-己烯的饱和率急剧增加。还发现噻吩（T），2-甲基噻吩（2MT）和3-甲基噻吩（3MT）强烈抑制氢化1-己烯。此外，对由有机硫化物脱硫产生的H 2 S产生的对1-己烯的抑制作用。在硫化合物存在下获得更多异构化产物，可能归因于抑制硫化合物对1-己烯及其异构体的氢化。

著录项

  • 来源
    《RSC Advances》 |2016年第39期|共7页
  • 作者

    Tu Chunyan; Li Mingfeng; Li Huifeng; Chu Yang; Liu Feng; Nie Hong; Li Dadong;

  • 作者单位

    SINOPEC Res Inst Petr Proc Beijing 100083 Peoples R China;

    SINOPEC Res Inst Petr Proc Beijing 100083 Peoples R China;

    SINOPEC Res Inst Petr Proc Beijing 100083 Peoples R China;

    SINOPEC Res Inst Petr Proc Beijing 100083 Peoples R China;

    SINOPEC Res Inst Petr Proc Beijing 100083 Peoples R China;

    SINOPEC Res Inst Petr Proc Beijing 100083 Peoples R China;

    SINOPEC Res Inst Petr Proc Beijing 100083 Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号